English
Karnataka Board PUCPUC Science Class 11

Pressure versus volume graph for a real gas and an ideal gas are shown in figure. Answer the following questions on the basis of this graph.Interpret the behaviour of real gas with res - Chemistry

Advertisements
Advertisements

Question

Pressure versus volume graph for a real gas and an ideal gas are shown in figure. Answer the following questions on the basis of this graph.

(i) Interpret the behaviour of real gas with respect to ideal gas at low pressure.

(ii) Interpret the behaviour of real gas with respect to ideal gas at high pressure.

(iii) Mark the pressure and volume by drawing a line at the point where real gas behaves as an ideal gas.

Short/Brief Note
Advertisements

Solution

(i) At low pressure, the curve of real gas coincides with that of ideal gas, this shows that the deviation of behaviour of real gas with respect to ideal gas is small or negligible.

(ii) At high pressure, the curve of real gas is far apart from ideal gas, this shows that the deviation of behaviour of real gas with respect to ideal gas is large.

(iii) The  pressure p1 and volume V1 are the point where real gas behaves as an ideal gas. 

shaalaa.com
  Is there an error in this question or solution?
Chapter 5: States of Matter - Multiple Choice Questions (Type - I) [Page 59]

APPEARS IN

NCERT Exemplar Chemistry [English] Class 11
Chapter 5 States of Matter
Multiple Choice Questions (Type - I) | Q 40 | Page 59

RELATED QUESTIONS

Which of the following is the correct expression for the equation of state of van der Waals gas?


The value of the universal gas constant depends upon


Compressibility factor for CO2 at 400 K and 71.0 bar is 0.8697. The molar volume of CO2 under these conditions is


Maximum deviation from ideal gas is expected from


Which of the following diagrams correctly describes the behaviour of a fixed mass of an ideal gas? (T is measured in K)


Suppose there is a tiny sticky area on the wall of a container of gas. Molecules hitting this area stick there permanently. Is the pressure greater or less than on the ordinary area of walls?


Explain whether a gas approaches ideal behavior or deviates from ideal behaviour if it is compressed to a smaller volume at a constant temperature.


Which of the following gases would you expect to deviate from ideal behavior under conditions of low-temperature F2, Cl2, or Br2? Explain.


A plot of volume (V) versus temperature (T) for a gas at constant pressure is a straight line passing through the origin. The plots at different values of pressure are shown in Figure. Which of the following order of pressure is correct for this gas?


Under which of the following two conditions applied together, a gas deviates most from the ideal behaviour?

(i) Low pressure

(ii) High pressure

(iii) Low temperature

(iv) High temperature


If 1 gram of each of the following gases are taken at STP, which of the gases will occupy (a) greatest volume and (b) smallest volume?

\[\ce{CO, H2O, CH4 , NO}\]


Value of universal gas constant (R) is same for all gases. What is its physical significance?


Compressibility factor, Z, of a gas is given as Z = `(pV)/(nRT)`. What is the value of Z for an ideal gas?


Compressibility factor, Z, of a gas is given as Z = `(pV)/(nRT)`. For real gas what will be the effect on value of Z above Boyle’s temperature?


Assertion (A): At constant temperature, pV vs V plot for real gases is not a straight line.

Reason (R): At high pressure all gases have \[\ce{Z}\] > 1 but at intermediate pressure most gases have \[\ce{Z}\] < 1.


In van der Waal's equation for the real gas, the expression for the net force of attraction amongst the gas molecules is given by:


Choose the correct option for the total pressure (in atm.) in a mixture of 4g \[\ce{O2}\] and 2g \[\ce{H2}\] confined in a total volume of one litre at 0°C is ______.

[Given R = 0.082 L atm mol−1K−1, T = 273 K]


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×