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Question
Predict the product of reaction of aniline with bromine in non-polar solvent such as \[\ce{CS2}\].
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Solution
In non-polar solvent (such as \[\ce{CS2}\]) the activating effect of -NH2 group is reduced (due to resonance) and hence, mono substitution occurs only at o- and p-positions.
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Illustrate the following reaction giving suitable example in each case: Diazotisation
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(i)
(ii)
(iii)
(iv)
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Statement I: Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at 273-278 K. It decomposes easily in the dry state.
Statement II: Insertion of iodine into the benzene ring is difficult and hence, iodobenzene is prepared through the reaction of benzenediazonium salt with KI.
In the light of the above statements, choose the most appropriate answer from the options given below:
