Advertisements
Advertisements
Question
Match the properties given in Column I with the metals given in Column II.
| Column I (Property) | Column II (Metal) | |
| (i) | Element with highest second ionisation enthalpy |
(a) \[\ce{Co}\] |
| (ii) | Element with highest third ionisation enthalpy |
(b) \[\ce{Cr}\] |
| (iii) | \[\ce{M}\] in \[\ce{M(CO)6}\] is | (c) \[\ce{Cu}\] |
| (iv) | Element with highest heat of atomisation |
(d) \[\ce{Zn}\] |
| (e) \[\ce{Ni}\] |
Advertisements
Solution
| Column I (Property) | Column II (Metal) | |
| (i) | Element with highest second ionisation enthalpy |
(c) \[\ce{Cu}\] |
| (ii) | Element with highest third ionisation enthalpy |
(d) \[\ce{Zn}\] |
| (iii) | \[\ce{M}\] in \[\ce{M(CO)6}\] is | (b) \[\ce{Cr}\] |
| (iv) | Element with highest heat of atomisation |
(a) \[\ce{Co}\] |
APPEARS IN
RELATED QUESTIONS
Why +2 oxidation state of manganese is more stable?
|
`E_((M^(2+)/M)` |
Cr | Mn | Fe | Co | Ni | Cu |
| -0.91 | -1.18 | -0.44 | -0.28 | -0.25 | -0.34 |
From the given data of E0 values, answer the following questions :
(1) Why is `E_(((Cu^(2+))/(Cu)))` value exceptionally positive
(2) Why is `E_(((Mn^(2+))/(Mn)))` value is highly negative as compared to other elements
(3) Which is the stronger reducing agents Cr2+ or Fe2+ ? Give Reason.
To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.
How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.
For M2+/M and M3+/M2+ systems, the EΘ values for some metals are as follows:
| Cr2+/Cr | −0.9 V |
| Mn2+/Mn | −1.2 V |
| Fe2+/Fe | −0.4 V |
| Cr3/Cr2+ | −0.4 V |
| Mn3+/Mn2+ | +1.5 V |
| Fe3+/Fe2+ | +0.8 V |
Use this data to comment upon:
The stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+.
Dissociation of H2S is suppressed in acidic medium.
When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.
Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they show similar physical and chemical properties because ______.
The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?
The halides of transition elements become more covalent with increasing oxidation state of the metal. Why?
Answer the following question:
Which element of the first transition series has highest second ionisation enthalpy?
Identify the metal and justify your answer.
Carbonyl \[\ce{M(CO)5}\]
Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:
(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)
Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.
The element with atomic number 53 belongs to
The basic character of transition metals monoxide follow the order.
Which one of the following characters tie of the transition metal is associated with higher catalytic activity?
Agcl is soluble in NH4OH. The solubility is due to the information of:-
The given graph shows the trends in melting points of transition metals:
Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.
Write the number of unpaired electrons in Cr3+.
(Atomic number of Cr = 24)
Give a reason for the following.
Some transition metals and their compounds get attracted towards the magnetic field.
