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प्रश्न
Match the properties given in Column I with the metals given in Column II.
| Column I (Property) | Column II (Metal) | |
| (i) | Element with highest second ionisation enthalpy |
(a) \[\ce{Co}\] |
| (ii) | Element with highest third ionisation enthalpy |
(b) \[\ce{Cr}\] |
| (iii) | \[\ce{M}\] in \[\ce{M(CO)6}\] is | (c) \[\ce{Cu}\] |
| (iv) | Element with highest heat of atomisation |
(d) \[\ce{Zn}\] |
| (e) \[\ce{Ni}\] |
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उत्तर
| Column I (Property) | Column II (Metal) | |
| (i) | Element with highest second ionisation enthalpy |
(c) \[\ce{Cu}\] |
| (ii) | Element with highest third ionisation enthalpy |
(d) \[\ce{Zn}\] |
| (iii) | \[\ce{M}\] in \[\ce{M(CO)6}\] is | (b) \[\ce{Cr}\] |
| (iv) | Element with highest heat of atomisation |
(a) \[\ce{Co}\] |
APPEARS IN
संबंधित प्रश्न
Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{ (aq)}}\] ion (Z = 27).
Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?
What is meant by ‘disproportionation’?
Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?
Write down the number of 3d electrons in the following ion:
Cu2+
Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).
Complete and balance the following chemical equations
`Fe^(2+) + MnO_4^(-) + H^+ ->`
Transition metals with lowest melting point is ______.
Highest oxidation state of manganese in fluoride is \[\ce{+4 (MnF4)}\] but highest oxidation state in oxides is \[\ce{+7 (Mn2O7)}\] because ______.
Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher oxidation states exceeds that of fluorine. Why?
Match the catalysts given in Column I with the processes given in Column II.
| Column I (Catalyst) | Column II (Process) |
| (i) \[\ce{Ni}\] in the presence of hydrogen | (a) Zieglar Natta catalyst |
| (ii) \[\ce{Cu2C12}\] | (b) Contact process |
| (iii) \[\ce{V2O5}\] | (c) Vegetable oil to ghee |
| (iv) Finely divided iron | (d) Sandmeyer reaction |
| (v) \[\ce{TiCl4 + Al (CH3)3}\] | (e) Haber's Process |
| (f) Decomposition of KCIO3 |
Identify A to E and also explain the reactions involved.

Identify the metal and justify your answer.
Carbonyl \[\ce{M(CO)5}\]
The product of oxidation of I– with \[\ce{MnO^{-}4}\] in alkaline medium is:-
The basic character of transition metals monoxide follow the order.
The number of terminal oxygen atoms present in the product B obtained from the following reactions is:
\[\ce{FeCr2O4 + Na2CO3 + O2 -> A + Fe2O3 + CO2}\]
\[\ce{A + H^+ -> B + H2O + Na^+}\]
Complete the following reaction and justify that it is a disproportionation reaction:
\[\ce{3MnO^{2-}4 + 4H^+ -> \underline{}\underline{}\underline{}\underline{} + \underline{}\underline{}\underline{}\underline{} + 2H2O}\]
The given graph shows the trends in melting points of transition metals:

Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.
A transition element X has an electronic configuration [Ar]4s23d3. Predict its likely oxidation states.
The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.
