हिंदी

Complete the following reaction and justify that it is a disproportionation reaction: 3MnOA42−+4HA+⟶――――+――――+2HA2O

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प्रश्न

Complete the following reaction and justify that it is a disproportionation reaction:

\[\ce{3MnO^{2-}4 + 4H^+ -> \underline{}\underline{}\underline{}\underline{} + \underline{}\underline{}\underline{}\underline{} + 2H2O}\]

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उत्तर

\[\ce{3MnO^{2-}4 + 4H^+ -> 2MnO^-4 + MnO2 + 2H2O}\]

This is a disproportionation reaction since the same element [Mn] is oxidised and reduced in this process.

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2022-2023 (March) Delhi Set 1

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संबंधित प्रश्न

Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Write the element which shows maximum number of oxidation states. Give reason.


How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.


For M2+/M and M3+/M2+ systems, the E° values for some metals are as follows:

Cr2+/Cr −0.9 V
Mn2+/Mn −1.2 V
Fe2+/Fe −0.4 V
Cr3/Cr2+ −0.4 V
Mn3+/Mn2+ +1.5 V
Fe3+/Fe2+ +0.8 V

Use this data to comment upon:

  1. The stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+ and
  2. the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

Compare the stability of +2 oxidation state for the elements of the first transition series.


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


Identify the metal and justify your answer.

\[\ce{MO3F}\]


The orientation of an atomic orbital is governed by


Which one of the following characters tie of the transition metal is associated with higher catalytic activity?


The E° value for the Mn2+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to the change of:


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