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प्रश्न
What may be the stable oxidation state of the transition element with the following d electron configurations in the ground state of its atom?
3d3
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उत्तर
The stable oxidation state will be +5 due to the outer electronic configuration 3d3 4s2 (+2, +3, +4, +5).
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संबंधित प्रश्न
Which of the following cations are coloured in aqueous solutions and why ?
Sc3+, V3+, Ti4+, Mn2+ (At. Nos. Sc = 21, V = 23, Ti = 22, Mn = 25)
Why do the transition elements have higher enthalpies of atomisation?
In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?
To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.
Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iodide.
For M2+/M and M3+/M2+ systems, the EΘ values for some metals are as follows:
| Cr2+/Cr | −0.9 V |
| Mn2+/Mn | −1.2 V |
| Fe2+/Fe | −0.4 V |
| Cr3/Cr2+ | −0.4 V |
| Mn3+/Mn2+ | +1.5 V |
| Fe3+/Fe2+ | +0.8 V |
Use this data to comment upon:
The stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+.
Complete and balance the following chemical equations
`MnO_4^(-) + H_2O + I^(-) ->`
Why do transition metals exhibit higher enthalpy of atomization?
Explain why transition elements form alloys.
\[\ce{KMnO4}\] acts as an oxidising agent in acidic medium. The number of moles of \[\ce{KMnO4}\] that will be needed to react with one mole of sulphide ions in acidic solution is ______.
Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher oxidation states exceeds that of fluorine. Why?
Assertion (A): Cu cannot liberate hydrogen from acids.
Reason (R): Because it has positive electrode potential.
Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:
(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)
Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.
Passing H2S gas into a mixture of Mn2+ and Ni2+, Cu2+, ions in an acidified aqueous solution precipitates.
Match List - I with List - II.
| List - I | List - II | ||
| (A) | [Fe(CN)6]3− | (i) | 5.92 BM |
| (B) | [Fe(H2O)6]3+ | (ii) | 0 BM |
| (C) | [Fe(CN)6]4− | (iii) | 4.90 BM |
| (D) | [Fe(H2O)6]2+ | (iv) | 1.73 BM |
Choose the correct answer from the options given below.
Why is the `"E"_(("V"^(3+)//"V"^(2+)))^"o"` value for vanadium comparatively low?
Which of the following transition metals shows +1 and +2 oxidation states?
Explain the magnetic properties of d-block (or transition) elements.
Give a reason for the following:
Transition metals possess a great tendency to form complex compounds.
Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with H2S.
