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Explain optical isomerism in 2-chlorobutane.

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Question

Explain optical isomerism in 2-chlorobutane.

Chemical Equations/Structures
Explain
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Solution

  1. The stereoisomerism in which the isomers have different spatial arrangements of groups/atoms around a chiral atom is called optical isomerism.
  2. 2-chlorobutane has one chiral carbon atom. The spatial arrangement of the four different groups around the chiral atom is different.
  3. Structure of 2-chlorobutane and its mirror image can be represented as:
  4. 2-Chlorobutane cannot superimpose perfectly on its mirror image as shown in the figure. Hence, 2-chlorobutane exhibits optical isomerism.
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Chapter 10: Halogen Derivatives - Exercises [Page 233]

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