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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Explain optical isomerism in 2-chlorobutane.

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प्रश्न

Explain optical isomerism in 2-chlorobutane.

रासायनिक समीकरणे/रचना
स्पष्ट करा
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उत्तर

  1. The stereoisomerism in which the isomers have different spatial arrangements of groups/atoms around a chiral atom is called optical isomerism.
  2. 2-chlorobutane has one chiral carbon atom. The spatial arrangement of the four different groups around the chiral atom is different.
  3. Structure of 2-chlorobutane and its mirror image can be represented as:
  4. 2-Chlorobutane cannot superimpose perfectly on its mirror image as shown in the figure. Hence, 2-chlorobutane exhibits optical isomerism.
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पाठ 10: Halogen Derivatives - Exercises [पृष्ठ २३३]

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a.

\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3}\\
|\phantom{.........}\\
\ce{OH}\phantom{.......}
\end{array}\]

b.

\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH2 - CH3}\\
|\phantom{..}\\
\ce{Br}\phantom{.}
\end{array}\]
c.

\[\ce{CH3 - CH2 - CH2 - CH2Br}\]

d.

\[\begin{array}{cc}
\ce{CH3 - CH - CH3 - CH3}\\
|\phantom{.........}\\
\ce{CH3}\phantom{.......}
\end{array}\]


Identify chiral molecule/s from the following.

a.

\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3}\\
|\phantom{.........}\\
\ce{OH}\phantom{.......}
\end{array}\]

b.

\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH2 - CH3}\\
|\phantom{.}\\
\phantom{.}\ce{Br}
\end{array}\]

c.

\[\ce{CH3 - CH2 - CH2 - CH2 Br}\]

d.

\[\begin{array}{cc}
\ce{CH3 - CH - CH3 - CH3}\\
|\phantom{.........}\\
\ce{CH3}\phantom{......}
\end{array}\]


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\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3}\\
|\phantom{.........}\\
\ce{OH}\phantom{.......}
\end{array}\]

b.

\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH2 - CH3}\\
|\phantom{..}\\
\ce{Br}\phantom{.}
\end{array}\]

c.

\[\begin{array}{cc}
\ce{CH3 - CH2 - CH2 - CH2 - Br}
\end{array}\]

d.

\[\begin{array}{cc}
\ce{CH3 - CH - CH3 - CH3}\\
|\phantom{.........}\\
\ce{CH3}\phantom{.......}
\end{array}\]


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