Advertisements
Advertisements
Question
Assertion: Order and molecularity are same.
Reason: Order is determined experimentally and molecularity is the sum of the stoichiometric coefficient of rate determining elementary step.
Options
Both assertion and reason are correct and the reason is correct explanation of assertion.
Both assertion and reason are correct but reason does not explain assertion.
Assertion is correct but reason is incorrect.
Both assertion and reason are incorrect.
Assertion is incorrect but reason is correct.
Advertisements
Solution
Assertion is incorrect but reason is correct.
Explanation:
Order and molecularity may not be necessarily same. Order is determined experimentally but molecularity is calculated using balanced stoichiometric equation.
APPEARS IN
RELATED QUESTIONS
Define “zero order reaction”.
What is pseudo first order reaction? Give one· example of it.
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
What is the overall order of reaction if A is present in large excess?
The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume :
SO2Cl2 (g) → SO2 (g) + Cl2 (g)
| Experiment | Time/s–1 | Total pressure/atm |
| 1 | 0 | 0.4 |
| 2 | 100 | 0.7 |
Calculate the rate constant.
(Given : log 4 = 0.6021, log 2 = 0.3010)
Mention the factors that affect the rate of a chemical reaction.
The decomposition of N2O5(g) at 320K according to the following equation follows first order reaction:
`N_2O_(5(g))->2NO_(2(g))+1/2O_(2(g))`
The initial concentration of N2O5(g) is 1.24 x 10-2 mol. L-1 and after 60 minutes 0.20x10-2 molL-1. Calculate the rate constant of the reaction at 320K.
In any unimolecular reaction:
(i) only one reacting species is involved in the rate determining step.
(ii) the order and the molecularity of slowest step are equal to one.
(iii) the molecularity of the reaction is one and order is zero.
(iv) both molecularity and order of the reaction are one.
For a general reaction A → B, plot of concentration of A vs time is given in figure. Answer the following question on the basis of this graph.
(i) What is the order of the reaction?
(ii) What is the slope of the curve?
(iii) What are the units of rate constant?
Why molecularity is applicable only for elementary reactions and order is applicable for elementary as well as complex reactions?
Assertion: Order of the reaction can be zero or fractional.
Reason: We cannot determine order from balanced chemical equation.
Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.
Reason: Reactant molecules undergo chemical change irrespective of their orientation during collision.
Use Molecular Orbital theory to determine the bond order in each of species, [He2j+ and [He2]2+?
For a reaction A + B → products, the rate law is given by: r = `K[A]^(1/2)`. What is the order of reaction?
If the 0.05 molar solution of m+ is replaced by a 0.0025 molar m+ solution, then the magnitude of the cell potential would be
At concentration of 0.1 and 0.2 mol L–1 the rates of deem position of a compound were found to be 0.18 and 0.72 mol L–1 m–1. What is the order of the reaction?
Identify the order of reaction from the following unit for its rate constant:
L mol–1 s–1
Which of the following statement is true?
A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half?
