Advertisements
Advertisements
Question
Answer the following in one or two sentences.
A solution concentration is expressed in molarity and not in molality while considering osmotic pressure. Why?
Advertisements
Solution
- Fraction `n/v` corresponds to the molarity (M) of a solution of a non-dissociating or totally dissociating solute `pi = n/v RT`
- Osmotic pressure increases by `1/273` for each degree of temperature increase.
- But osmotic pressure measurements are made at specific constant temperatures. In this case, M remains constant.
`M = n_2/V` [Temp. dependent]
`m = n_2/W_1` [Temp. independent]
APPEARS IN
RELATED QUESTIONS
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
Which of the following is not a colligative property?
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.
Define osmotic pressure.
Define Semipermeable membrane
Define the following term:
isotonic solution
Define the following term:
Hypotonic solution
Choose the most correct option.
In calculating osmotic pressure the concentration of solute is expressed in _______.
Choose the most correct option.
The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.
Answer the following in one or two sentences.
What is osmotic pressure?
Answer the following.
A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.
Answer the following.
The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.
Answer the following.
How molar mass of a solute is determined by osmotic pressure measurement?
An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?
What are hypertonic solutions?
Explain the phenomenon of osmosis.
Define Osmosis.
Which of the following is a colligative property?
The average osmotic pressure of human blood is 7.8 bar at 37°C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream?
Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be:
A solution containing 10 g per dm3 of urea (molar mass 60 g mol−1) is isotonic with 5% solution of non-volatile solute, MB of solute is:
The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic pressure of 16.4 atoms is: (R = 0.082 L atom K−1 mol−1)
At a given temperature, osmotic pressure of a concentrated solution of a substance ______.
Which of the following statements is false?
Isotonic solutions must have the same:
(i) solute
(ii) density
(iii) elevation in boiling point
(iv) depression in freezing point
In isotonic solutions:
(i) Solute and solvent both are same.
(ii) Osmotic pressure is same.
(iii) Solute and solvent may or may not be same.
(iv) Solute is always same solvent may be different.
Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.
Match the items given in Column I and Column II.
| Column I | Column II |
| (i) Saturated solution | (a) Solution having same osmotic pressure at a given temperature as that of given solution. |
| (ii) Binary solution | (b) A solution whose osmotic pressure is less than that of another. |
| (iii) Isotonic solution | (c) Solution with two components. |
| (iv) Hypotonic solution | (d) A solution which contains maximum amount of solute that can be dissolved in a given amount of solvent at a given temperature. |
| (v) Solid solution | (e) A solution whose osmotic pressure is more than that of another. |
| (vi) Hypertonic solution | (f) A solution in solid phase. |
Discuss biological and industrial importance of osmosis.
How can you remove the hard calcium carbonate layer of the egg without damaging its semiprermiable membrane? Can this egg be inserted into a bottle with a narrow neck without distorting its shape? Explain the process involved.
Osmotic pressure of a solution increases if
The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is
Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Isotonic solutions are the solutions having the same ______.
A solution containing 10 g glucose has osmotic pressure 3.84 atm. If 10 g more glucose is added to the same solution, what will be its osmotic pressure? (Temperature remains constant)
Name the four colligative properties that are oftently used for determination of molecular mass.
Write the condition of reverse osmosis.
Calculate the osmotic pressure of 0.03 mole of non electrolyte solute dissolved in 0.1 dm3 of water at 300 K. [R = 0.082 dm3 atm mol-1 K-1]
The 'X' g nonvolatile solute having molar mass 196 g mol-1 is dissolved in 3 dm³ water. Calculate the value of 'X' if resulting solution has osmotic pressure 0.8 atm at 300 К.
(R = 0.0821dm³ atm K-1 mol-1)
Calculate the osmotic pressure of 0.2 M aqueous solution of nonelectrolyte at 300 K.
[R = 0.082 atm dm3 mol−1K−1]
