Advertisements
Advertisements
Question
Answer the following.
The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.
Advertisements
Solution
Given: Osmotic pressure of CaCl2 solution = 0.605 atm
Osmotic pressure of urea solution = 0.245 atm
To find: The value of van’t Hoff factor
Formulae: π = MRT, π = iMRT
Calculation: For urea solution
π = MRT
0.245 atm = MRT ....(i)
For CaCl2 solution
π = iMRT
0.605 atm = iMRT ....(ii)
From equations (i) and (ii),
`0.605/0.245 = "iMRT"/"MRT"`
∴ i = 2.47
The value of van’t Hoff factor is 2.47.
APPEARS IN
RELATED QUESTIONS
Which of the following is not a colligative property?
Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution?
A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Define osmotic pressure.
Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?
Define Semipermeable membrane
Calculate the mass of NaCl (molar mass = 58.5 g mol−1) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete dissociation. (Kf for water = 1.86 K kg mol−1)
Define the following term:
isotonic solution
Define the following term:
Hypotonic solution
Choose the most correct option.
The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.
Answer the following in one or two sentences.
A solution concentration is expressed in molarity and not in molality while considering osmotic pressure. Why?
Answer the following.
What are isotonic and hypertonic solutions?
Answer the following.
A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.
Answer the following.
Explain reverse osmosis.
Which of the following statements is applicable for 0.1 M urea solution and 0.1 M sucrose solution?
What are hypertonic solutions?
Explain the phenomenon of osmosis.
Which of the following is a colligative property?
Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.
20 g of a substance were dissolved in 500 mL of water and the osmotic pressure of the solution was found to be 600 mm of mercury at 15°C. The molecular weight of the substance is:
The average osmotic pressure of human blood is 7.8 bar at 37°C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream?
At a given temperature, osmotic pressure of a concentrated solution of a substance ______.
Which of the following statements is false?
Isotonic solutions must have the same:
(i) solute
(ii) density
(iii) elevation in boiling point
(iv) depression in freezing point
In isotonic solutions:
(i) Solute and solvent both are same.
(ii) Osmotic pressure is same.
(iii) Solute and solvent may or may not be same.
(iv) Solute is always same solvent may be different.
Match the items given in Column I and Column II.
| Column I | Column II |
| (i) Saturated solution | (a) Solution having same osmotic pressure at a given temperature as that of given solution. |
| (ii) Binary solution | (b) A solution whose osmotic pressure is less than that of another. |
| (iii) Isotonic solution | (c) Solution with two components. |
| (iv) Hypotonic solution | (d) A solution which contains maximum amount of solute that can be dissolved in a given amount of solvent at a given temperature. |
| (v) Solid solution | (e) A solution whose osmotic pressure is more than that of another. |
| (vi) Hypertonic solution | (f) A solution in solid phase. |
Osmotic pressure of a solution increases if
Isotonic solutions have same
Which one of the following is a colligative property?
Blood cells retain their normal shape in solution which are
In Isotonic solution
The vapour pressure of water is 12.3 k pa at 300 k. Calculated the vapour pressure of molal solution in it.
The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is
Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.
(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)
Prove that: M2 = `(W_2RT)/(πV)`.
Arrange the following solutions in the order of increasing osmotic pressure (π) assuming complete ionization.
- 0.5M Li2 SO4
- 0.5M KCl
- 0.5M Al2 (SO4)3
- 0.1 M BaCl2
Name the four colligative properties that are oftently used for determination of molecular mass.
How will you determine molar mass of solute from osmotic pressure?
Write the condition of reverse osmosis.
