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प्रश्न
Why can’t molecularity of any reaction be equal to zero?
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उत्तर
The number of molecules of the reactants involved in an elementary reaction is referred to as the molecularity of the reaction. For this, a single molecule with a minimum molecularity of one is required, and it cannot be zero.
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संबंधित प्रश्न
A → B is a first order reaction with rate 6.6 × 10-5m-s-1. When [A] is 0.6m, rate constant of the reaction is
- 1.1 × 10-5s-1
- 1.1 × 10-4s-1
- 9 × 10-5s-1
- 9 × 10-4s-1
For a reaction: 
Rate = k
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.
For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :
| t/s | 0 | 30 | 60 |
| [CH3COOCH3] / mol L–1 | 0.60 | 0.30 | 0.15 |
(i) Show that it follows pseudo first order reaction, as the concentration of water remains constant.
(ii) Calculate the average rate of reaction between the time interval 30 to 60 seconds.
(Given log 2 = 0.3010, log 4 = 0.6021)
For a reaction, \[\ce{A + B -> Product}\]; the rate law is given by, `r = k[A]^(1/2)[B]^2`. What is the order of the reaction?
From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.
\[\ce{CH3CHO_{(g)} -> CH4_{(g)} + CO_{(g)}}\] Rate = k [CH3CHO]3/2
For the reaction:
\[\ce{2A + B → A2B}\]
the rate = k[A][B]2 with k = 2.0 × 10−6 mol−2 L2 s−1. Calculate the initial rate of the reaction when [A] = 0.1 mol L−1, [B] = 0.2 mol L−1. Calculate the rate of reaction after [A] is reduced to 0.06 mol L−1.
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Which of the following statement is true for order of a reaction?
Consider a first order gas phase decomposition reaction given below :
\[\ce{A(g) -> B(g) + C(g)}\]
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure of the system increased by x units and became ‘pt’ The rate constant k for the reaction is given as ______.
Rate law for the reaction \[\ce{A + 2B -> C}\] is found to be Rate = k [A][B]. Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be ______.
For a complex reaction:
(i) order of overall reaction is same as molecularity of the slowest step.
(ii) order of overall reaction is less than the molecularity of the slowest step.
(iii) order of overall reaction is greater than molecularity of the slowest step.
(iv) molecularity of the slowest step is never zero or non interger.
In a reaction if the concentration of reactant A is tripled, the rate of reaction becomes twenty seven times. What is the order of the reaction?
Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.
Reason: Reactant molecules undergo chemical change irrespective of their orientation during collision.
A catalyst in a reaction changes which of the following?
The rate constant for the reaction \[\ce{2H2O5 -> 4NO2 + O2}\] is 30 × 10–5 sec–1. if the rate is 204 × 10–5 mol L–1 S–1, then the concentration of N2O5 (in mol–1) is-
For the reaction, \[\ce{A +2B → AB2}\], the order w.r.t. reactant A is 2 and w.r.t. reactant B. What will be change in rate of reaction if the concentration of A is doubled and B is halved?
Read the following passage and answer the questions that follow:
|
The rate of reaction is concerned with decrease in the concentration of reactants or increase in the concentration of products per unit of time. It can be expressed as instantaneous rate at a particular instant of time and average rate over a large interval of time. A number of factors such as temperature, concentration of reactants, catalyst affect the rate of reaction. Mathematical representation of rate of a reaction is given by rate law: Rate = k[A]x [B]y x and y indicate how sensitive the rate is to change in concentration of A and B. Sum of x + y gives the overall order of a reaction. |
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- How order and molecularity are different for complex reactions? [1]
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OR
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