Advertisements
Advertisements
प्रश्न
A reaction is first order in A and second order in B. How is the rate affected when the concentrations of both A and B are doubled?
A reaction is of first order with respect to reactant [A] and second order with regard to reactant [B]. What is the effect on rate of reaction when concentrations of both [A] and [B] are doubled?
Advertisements
उत्तर
When the concentrations of both A and B are doubled,
Rate = k(2a) (2b)2
= k(2a) (4b2)
= 8 kab2
∴ The reaction rate will increase by a factor of 8.
संबंधित प्रश्न
Define “zero order reaction”.
For a reaction: 
Rate = k
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
How is the rate of reaction affected if the concentration of B is doubled?
For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as:
(i) Predict the order of the reaction.
(ii) What is the slope of the curve?
(iii) Write the unit of rate constant for this reaction.
Mention the factors that affect the rate of a chemical reaction.
Molecularity of a reaction _____________.
Consider the reaction A ⇌ B. The concentration of both the reactants and the products varies exponentially with time. Which of the following figures correctly describes the change in concentration of reactants and products with time?
In any unimolecular reaction:
(i) only one reacting species is involved in the rate determining step.
(ii) the order and the molecularity of slowest step are equal to one.
(iii) the molecularity of the reaction is one and order is zero.
(iv) both molecularity and order of the reaction are one.
Why does the rate of any reaction generally decreases during the course of the reaction?
Why can’t molecularity of any reaction be equal to zero?
Why molecularity is applicable only for elementary reactions and order is applicable for elementary as well as complex reactions?
Why can we not determine the order of a reaction by taking into consideration the balanced chemical equation?
Match the graph given in Column I with the order of reaction given in Column II. More than one item in Column I may link to the same item of Column II.
| Column I | Column II | |
| (i) |  |
|
| (ii) |  |
(a) 1st order |
| (iii) |  |
(b) Zero-order |
| (iv) |  |
At concentration of 0.1 and 0.2 mol L–1 the rates of deem position of a compound were found to be 0.18 and 0.72 mol L–1 m–1. What is the order of the reaction?
A drop of solution (volume 0.05 ml) contains 3.0 × 10-6 mole of H+. If the rate constant of disappearance of H+ is 1.0 × 107 mole l-1s-1. It would take for H+ in drop to disappear in ______ × 10-9s.
A flask contains a mixture of compounds A and B. Both compounds decompose by first-order kinetics. The half-lives for A and B are 300 s and 180 s, respectively. If the concentrations of A and B are equal initially, the time required for the concentration of A to be four times that of B (in s) is ______. (Use ln 2 = 0.693)
Which of the following statement is true?
