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प्रश्न
Define the following term:
Pseudo first-order reaction
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उत्तर
The reactions that have higher order true rate law but are found to behave as first order are called pseudo first order reactions.
\[\ce{CH3COOCH3 + H2O - CH3COOH + CH3OH}\]
संबंधित प्रश्न
The conversion of molecules X to Y follows second order kinetics. If concentration of X is increased to three times how will it affect the rate of formation of Y?
From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.
\[\ce{H2O2_{( aq)} + 3I^-_{( aq)} + 2H^+ -> 2H2O_{(l)} + I^-_3}\] Rate = k[H2O2][I−]
Molecularity of a reaction _____________.
Why can we not determine the order of a reaction by taking into consideration the balanced chemical equation?
Assertion: Order and molecularity are same.
Reason: Order is determined experimentally and molecularity is the sum of the stoichiometric coefficient of rate determining elementary step.
Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.
Reason: Reactant molecules undergo chemical change irrespective of their orientation during collision.
Use Molecular Orbital theory to determine the bond order in each of species, [He2j+ and [He2]2+?
Read the following passage and answer the questions that follow:
|
The rate of reaction is concerned with decrease in the concentration of reactants or increase in the concentration of products per unit of time. It can be expressed as instantaneous rate at a particular instant of time and average rate over a large interval of time. A number of factors such as temperature, concentration of reactants, catalyst affect the rate of reaction. Mathematical representation of rate of a reaction is given by rate law: Rate = k[A]x [B]y x and y indicate how sensitive the rate is to change in concentration of A and B. Sum of x + y gives the overall order of a reaction. |
- What is the effect of temperature on the rate constant of a reason? [1]
- For a reaction \[\ce{A + B → Product}\], the rate law is given by, Rate = k[A]2 [B]1/2. What is the order of the reaction? [1]
- How order and molecularity are different for complex reactions? [1]
- A first-order reaction has a rate constant 2 × 10–3 s–1. How long will 6 g of this reactant take to reduce to 2 g? [2]
OR
The half-life for radioactive decay of 14C is 6930 years. An archaeological artifact containing wood had only 75% of the 14C found in a living tree. Find the age of the sample.
[log 4 = 0.6021, log 3 = 0.4771, log 2 = 0.3010, log 10 = 1] [2]
On heating compound (A) gives a gas (B) which is constituent of air. The gas when treated with H2 in the presence of catalyst gives another gas (C) which is basic in nature, (A) should not be ______.
Higher yield of NO in \[\ce{N2(g) + O2 <=> 2NO(g)}\] can be obtained at:
[ΔH of the reaction = +180.7 kJ mol−1]
- higher temperature
- lower temperature
- higher concentration of N2
- higher concentration of O2
Choose the correct answer from the options given below:
