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प्रश्न
Define the following term:
Pseudo first-order reaction
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उत्तर
The reactions that have higher order true rate law but are found to behave as first order are called pseudo first order reactions.
\[\ce{CH3COOCH3 + H2O - CH3COOH + CH3OH}\]
संबंधित प्रश्न
In a first order reaction x → y, 40% of the given sample of compound remains unreacted in 45 minutes. Calculate rate constant of the reaction.
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
How is the rate of reaction affected if the concentration of B is doubled?
Compounds ‘A’ and ‘B’ react according to the following chemical equation.
\[\ce{A(g) + 2B(g) -> 2C(g)}\]
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants constant and rates were measured as a function of initial concentration. Following results were obtained. Choose the correct option for the rate equations for this reaction.
| Experiment | Initial concentration of [A]/mol L–¹ |
Initial concentration of [B]/mol L–¹ |
Initial rate of formation of [C]/mol L–¹ s–¹ |
| 1. | 0.30 | 0.30 | 0.10 |
| 2. | 0.30 | 0.60 | 0.40 |
| 3. | 0.60 | 0.30 | 0.20 |
Consider the reaction A ⇌ B. The concentration of both the reactants and the products varies exponentially with time. Which of the following figures correctly describes the change in concentration of reactants and products with time?
Assertion: The enthalpy of reaction remains constant in the presence of a catalyst.
Reason: A catalyst participating in the reaction, forms different activated complex and lowers down the activation energy but the difference in energy of reactant and product remains the same.
Use Molecular Orbital theory to determine the bond order in each of species, [He2j+ and [He2]2+?
A catalyst in a reaction changes which of the following?
For a reaction R → p the concentration of reactant change from 0.03 m to 0.02 m in minute, calculate the average rate of the reaction using the unit of second.
For a reaction \[\ce{Cl2l(g) + 2No(g) -> 2NaCl(g)}\] the rate law is expressed as rate= K[Cl2] [No]2 what is the order of the reaction?
The conversion of molecules A to B follow second order kinetics. If concentration of A is increased to three times, how will it affect the rate of formation of B?
