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Define the Following Terms: Half-life Period of Reaction (T1/2). - Chemistry

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प्रश्न

Define the following terms:

Half-life period of reaction (t1/2).

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उत्तर

 Half-life period of a reaction
Half-life period of a reaction is the time taken for half of the reaction to be completed. In other words, the time in which the concentration of a reactant is reduced to half of its original value is called half-life period of the reaction.
For  zero-order reaction,
For first-order reaction,
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2013-2014 (March) Delhi Set 2

व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

In a first order reaction x → y, 40% of the given sample of compound remains unreacted in 45 minutes. Calculate rate constant of the reaction.


A → B is a first order reaction with rate 6.6 × 10-5m-s-1. When [A] is 0.6m, rate constant of the reaction is

  • 1.1 × 10-5s-1
  • 1.1 × 10-4s-1
  • 9 × 10-5s-1
  • 9 × 10-4s-1

From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{H2O2_{( aq)} + 3I^-_{( aq)} + 2H^+ -> 2H2O_{(l)} + I^-_3}\] Rate = k[H2O2][I]


Why molecularity is applicable only for elementary reactions and order is applicable for elementary as well as complex reactions?


Why can we not determine the order of a reaction by taking into consideration the balanced chemical equation?


Match the graph given in Column I with the order of reaction given in Column II. More than one item in Column I may link to the same item of Column II.

  Column I Column II
(i)  
(ii)  (a) 1st order
(iii) (b) Zero-order
(iv)    

Assertion: Order of the reaction can be zero or fractional.

Reason: We cannot determine order from balanced chemical equation.


Identify the order of reaction from the following unit for its rate constant:

L mol–1 s–1


The following data was obtained for chemical reaction given below at 975 K.

\[\ce{2NO(g) + 2H2(g) -> N2(g) + 2H2O(g)}\]

  [NO] [H2] Rate
  Mol L-1 Mol L-1 Mol L-1 s-1
(1) 8 × 10-5 8 × 10-5 7 × 10-9
(2) 24 × 10-5 8 × 10-5 2.1 × 10-8
(3) 24 × 10-5 32 × 10-5 8.4 × 10-8

The order of the reaction with respect to NO is ______. (Integer answer)


Higher yield of NO in \[\ce{N2(g) + O2 <=> 2NO(g)}\] can be obtained at:

[ΔH of the reaction = +180.7 kJ mol−1]

  1. higher temperature
  2. lower temperature
  3. higher concentration of N2
  4. higher concentration of O2

Choose the correct answer from the options given below:


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