Advertisements
Advertisements
प्रश्न
Account for the following:
Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
Advertisements
उत्तर
Due to the +I effect of −CH3 group, methylamine is more basic than water. Therefore, in water, methylamine produces OH− ions by accepting H+ ions from water.
\[\ce{CH3-NH2 + H-OH -> H3N+-CH3 + OH-}\]
Ferric chloride (FeCl3) dissociates in water to form Fe3+ and Cl− ions.
Then, OH− ion reacts with Fe3+ ion to form a precipitate of hydrated ferric oxide.
\[\ce{FeCl3 -> Fe^{3+} + 3Cl^-}\]
\[\ce{2Fe^{3+} + 6OH^- -> \underset{(Brown precipitate)}{Fe2O3.3H2O}}\]
संबंधित प्रश्न
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
CH3(CH2)2NH2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
(CH3)3CNH2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
C6H5NHCH3
Give one chemical test to distinguish between the following pair of compounds.
Methylamine and dimethylamine
How will you convert methanol to ethanoic acid?
How will you convert nitromethane into dimethylamine?
How will you convert propanoic acid into ethanoic acid?
Accomplish the following conversion:
Benzoic acid to aniline
Accomplish the following conversion:
Chlorobenzene to p-chloroaniline
Accomplish the following conversion:
Aniline to benzyl alcohol
Give reasons Although –NH2 is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline
Do the following conversions in not more than two steps :
Propanone to Propene
What is the action of p-toluenesulphonychloride on ethylamine and diethylamine?
The following amine is called as:

Identify the incorrect IUPAC name.
Predict the product 'A' in the following reaction.
\[\ce{\underset{(Acetyl chloride)}{CH3COCl}->[H2][Pd-BaSO4]A + HCl}\]
