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प्रश्न
Account for the following:
Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
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उत्तर
Due to the +I effect of −CH3 group, methylamine is more basic than water. Therefore, in water, methylamine produces OH− ions by accepting H+ ions from water.
\[\ce{CH3-NH2 + H-OH -> H3N+-CH3 + OH-}\]
Ferric chloride (FeCl3) dissociates in water to form Fe3+ and Cl− ions.
Then, OH− ion reacts with Fe3+ ion to form a precipitate of hydrated ferric oxide.
\[\ce{FeCl3 -> Fe^{3+} + 3Cl^-}\]
\[\ce{2Fe^{3+} + 6OH^- -> \underset{(Brown precipitate)}{Fe2O3.3H2O}}\]
संबंधित प्रश्न
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
CH3NHCH(CH3)2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
C6H5NHCH3
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
m−BrC6H4NH2
Give one chemical test to distinguish between the following pair of compounds.
Ethylamine and aniline
Account for the following:
Ethylamine is soluble in water, whereas aniline is not.
How will you convert hexanenitrile into 1-aminopentane?
How will you convert methanol to ethanoic acid?
How will you convert ethanamine into methanamine?
Accomplish the following conversion:
Aniline to 2, 4, 6-tribromofluorobenzene
Complete the following reaction:
\[\ce{C6H5N2Cl + C2H5OH ->}\]
Complete the following reaction:
\[\ce{C6H5N2Cl ->[(i) HBF4][(ii) NaNO2/Cu, \Delta]}\]
Give reasons Although –NH2 is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline
How are ethylamine and ethyl methyl amine distinguished by using nitrous acid?
Write the IUPAC name of the given compound :
Using IUPAC norms, write the formula of Hexaamminecobalt(III) sulphate.
Identify the incorrect IUPAC name.
