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Account for the following: Ethylamine is soluble in water, whereas aniline is not. - Chemistry

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प्रश्न

Account for the following:

Ethylamine is soluble in water, whereas aniline is not.

रासायनिक समीकरण/संरचनाएँ
लघु उत्तरीय
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उत्तर

Ethylamine is soluble in water, due to hydrogen bonding as shown below:

\[\begin{array}{cc}
\ce{H}\phantom{..........................}\ce{H}\phantom{.................}\\
|\phantom{...........................}|\phantom{.................}\\
\ce{{- - - - - -} N-H {- - - - - -} O-H {- - - - - -} N-H {- - - - - -} O-H {- - - - - -}}\\
\phantom{..........}|\phantom{.............}|\phantom{..............}|\phantom{.............}|\phantom{.............}\\
\ce{\underset{Ethylamine}{C2H5}}\phantom{.......}\ce{H}\phantom{.............}\ce{C2H5}\phantom{.........}\ce{H}\phantom{.....}
\end{array}\]

On the other hand, aniline has a large phenyl group and has -I effect due to which the hydrogen bonding with water is reduced. Hence, aniline is insoluble in water.

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अध्याय 9: Amines - Exercises [पृष्ठ २७८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 9 Amines
Exercises | Q 9.3 (ii) | पृष्ठ २७८

संबंधित प्रश्न

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(a) C6H12N4

(b) C6H24H4                    

(c) C6H12N4O2

(d) C6H24N4O2


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