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प्रश्न
Account for the following:
Ethylamine is soluble in water, whereas aniline is not.
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उत्तर
Ethylamine is soluble in water, due to hydrogen bonding as shown below:
\[\begin{array}{cc}
\ce{H}\phantom{..........................}\ce{H}\phantom{.................}\\
|\phantom{...........................}|\phantom{.................}\\
\ce{{- - - - - -} N-H {- - - - - -} O-H {- - - - - -} N-H {- - - - - -} O-H {- - - - - -}}\\
\phantom{..........}|\phantom{.............}|\phantom{..............}|\phantom{.............}|\phantom{.............}\\
\ce{\underset{Ethylamine}{C2H5}}\phantom{.......}\ce{H}\phantom{.............}\ce{C2H5}\phantom{.........}\ce{H}\phantom{.....}
\end{array}\]
On the other hand, aniline has a large phenyl group and has -I effect due to which the hydrogen bonding with water is reduced. Hence, aniline is insoluble in water.
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संबंधित प्रश्न
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Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
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Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
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Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
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Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
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Give one chemical test to distinguish between the following pair of compounds.
Aniline and N-methylaniline
Account for the following:
pKb of aniline is more than that of methylamine.
Account for the following:
Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
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Complete the following reaction:
\[\ce{C6H5N2Cl + C2H5OH ->}\]
Do the following conversions in not more than two steps :
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Identify the incorrect IUPAC name.
An organic compound (A) with molecular formula C3H7NO on heating with Br2 and KOH forms a compound (B). Compound (B) on heating with CHCl3 and alcoholic KOH produces a foul-smelling compound (C) and on reacting with C6H5SO2Cl forms a compound (D) which is soluble in alkali. Write the structure of (A), (B), (C) and (D).
