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प्रश्न
How are ethylamine and ethyl methyl amine distinguished by using nitrous acid?
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उत्तर
An action of nitrous acid on ethylamine
An action of nitrous acid on ethylmethylamine
When the nitrous acid reacts with primary amine like C2H5NH2 it gives ethanol while when nitrous acid reactions with secondary amine like ethylmethylamine it gives yellow oily N-nitrosamine.
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संबंधित प्रश्न
Which among the following molecular formulae represents urotropine?
(a) C6H12N4
(b) C6H24H4
(c) C6H12N4O2
(d) C6H24N4O2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
(CH3)2CHNH2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
CH3(CH2)2NH2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
C6H5NHCH3
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
m−BrC6H4NH2
Account for the following:
pKb of aniline is more than that of methylamine.
Account for the following:
Ethylamine is soluble in water, whereas aniline is not.
How will you convert hexanenitrile into 1-aminopentane?
How will you convert ethanoic acid into propanoic acid?
How will you convert propanoic acid into ethanoic acid?
Accomplish the following conversion:
Benzoic acid to aniline
Accomplish the following conversion:
Chlorobenzene to p-chloroaniline
An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of molecular formula C6H7N. Write the structures and IUPAC names of compounds A, B and C.
Complete the following reaction:
\[\ce{C6H5NH2 + H2SO4 (conc.)}\]
Complete the following reaction:
\[\ce{C6H5N2Cl + C2H5OH ->}\]
Complete the following reaction:
\[\ce{C6H5NH2 + (CH3CO)2O ->}\]
Complete the following reaction:
\[\ce{C6H5N2Cl ->[(i) HBF4][(ii) NaNO2/Cu, \Delta]}\]
Do the following conversions in not more than two steps :
Propanone to Propene
Write the structure of 2,4-dinitrochlorobenzene
What is the action of p-toluenesulphonychloride on ethylamine and diethylamine?
Using IUPAC norms, write the formula of Hexaamminecobalt(III) sulphate.
Identify the incorrect IUPAC name.
An organic compound (A) with molecular formula C3H7NO on heating with Br2 and KOH forms a compound (B). Compound (B) on heating with CHCl3 and alcoholic KOH produces a foul-smelling compound (C) and on reacting with C6H5SO2Cl forms a compound (D) which is soluble in alkali. Write the structure of (A), (B), (C) and (D).
Do the following conversions in not more than two steps:
\[\begin{array}{cc}
\ce{CH3CN to CH3 - C - CH3}\\
\phantom{...........}||\\
\phantom{...........}\ce{O}
\end{array}\]
Predict the product 'A' in the following reaction.
\[\ce{\underset{(Acetyl chloride)}{CH3COCl}->[H2][Pd-BaSO4]A + HCl}\]
