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Give one chemical test to distinguish between the following pair of compounds. Secondary and tertiary amines - Chemistry

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प्रश्न

Give one chemical test to distinguish between the following pair of compounds.

Secondary and tertiary amines

रासायनिक समीकरण/संरचनाएँ
अंतर स्पष्ट करें
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उत्तर

Secondary and tertiary amines can be distinguished by allowing them to react with Hinsberg’s reagent (benzenesulphonyl chloride, C6H5SO2Cl).

Secondary amines react with Hinsberg’s reagent to form a product that is insoluble in an alkali. For example, N, N−diethylamine reacts with Hinsberg’s reagent to form N, N−diethylbenzenesulphonamide, which is insoluble in an alkali. Tertiary amines, however, do not react with Hinsberg’s reagent.

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अध्याय 9: Amines - Exercises [पृष्ठ २७८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 9 Amines
Exercises | Q 9.2 (ii) | पृष्ठ २७८

संबंधित प्रश्न

Convert 3-Methylaniline into 3-nitrotoluene.


Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.

(CH3)3CNH2


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C6H5NHCH3


Give one chemical test to distinguish between the following pair of compounds.

Ethylamine and aniline


Give one chemical test to distinguish between the following pair of compounds.

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Account for the following:

Ethylamine is soluble in water, whereas aniline is not.


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How will you convert ethanamine into methanamine?


How will you convert nitromethane into dimethylamine?


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Complete the following reaction:

\[\ce{C6H5N2Cl + C2H5OH ->}\]


Complete the following reaction:

\[\ce{C6H5NH2 + Br2 (aq) ->}\]


Complete the following reaction:

\[\ce{C6H5N2Cl ->[(i) HBF4][(ii) NaNO2/Cu, \Delta]}\]


Do the following conversions in not more than two steps :

Ethyl benzene to Benzoic acid


Do the following conversions in not more than two steps :

Propanone to Propene


Using IUPAC norms, write the formula of Hexaamminecobalt(III) sulphate.


An organic compound (A) with molecular formula C3H7NO on heating with Br2 and KOH forms a compound (B). Compound (B) on heating with CHCl3 and alcoholic KOH produces a foul-smelling compound (C) and on reacting with C6H5SO2Cl forms a compound (D) which is soluble in alkali. Write the structure of (A), (B), (C) and (D).


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