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प्रश्न
Give one chemical test to distinguish between the following pair of compounds.
Secondary and tertiary amines
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उत्तर
Secondary and tertiary amines can be distinguished by allowing them to react with Hinsberg’s reagent (benzenesulphonyl chloride, C6H5SO2Cl).
Secondary amines react with Hinsberg’s reagent to form a product that is insoluble in an alkali. For example, N, N−diethylamine reacts with Hinsberg’s reagent to form N, N−diethylbenzenesulphonamide, which is insoluble in an alkali. Tertiary amines, however, do not react with Hinsberg’s reagent.
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संबंधित प्रश्न
Which among the following molecular formulae represents urotropine?
(a) C6H12N4
(b) C6H24H4
(c) C6H12N4O2
(d) C6H24N4O2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
CH3(CH2)2NH2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
CH3NHCH(CH3)2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
(CH3)3CNH2
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
C6H5NHCH3
Account for the following:
pKb of aniline is more than that of methylamine.
Account for the following:
Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
How will you convert hexanenitrile into 1-aminopentane?
How will you convert nitromethane into dimethylamine?
How will you convert propanoic acid into ethanoic acid?
Accomplish the following conversion:
Aniline to 2, 4, 6-tribromofluorobenzene
Accomplish the following conversion:
Aniline to benzyl alcohol
Complete the following reaction:
\[\ce{C6H5NH2 + H2SO4 (conc.)}\]
Complete the following reaction:
\[\ce{C6H5NH2 + Br2 (aq) ->}\]
Write the IUPAC name of the given compound :
The following amine is called as:
Identify the incorrect IUPAC name.
Do the following conversions in not more than two steps:
\[\begin{array}{cc}
\ce{CH3CN to CH3 - C - CH3}\\
\phantom{...........}||\\
\phantom{...........}\ce{O}
\end{array}\]
