Advertisements
Advertisements
प्रश्न
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
K[Cr(H2O)2(C2O4)2].3H2O
Advertisements
उत्तर
| IUPAC name of the hybrid compound | Oxidation state of the central metal | Coordination number | Shape | Central metal ion | Electronic configuration | The value of n and the magnetic moment |
| Potassium diaquadioxalatochromate(III) hydrate | −1 + x + 2 × (0) + 2 × (−2) = 0 ∴ x = +3 |
6 | Octahedral | Cr3+ |
3d3, \[\ce{t^3_{2g}e^0_g}\] |
n = 3, `sqrt(3(3 + 2))` = 3.87 BM |
Stereochemistry:
APPEARS IN
संबंधित प्रश्न
For the complex [Fe(CN)6]3–, write the hybridization type, magnetic character and spin nature of the complex. (At. number : Fe = 26).
Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].
(At.no. of Ni = 28)
Write the hybridization and shape of the following complexe : [CoF6]3–
(Atomic number : Co = 27, Ni = 28)
Write the hybridization and shape of the following complexe : [Ni(CN)4]2–
(Atomic number : Co = 27, Ni = 28)
Explain [Co(NH3)6]3+ is an inner orbital complex, whereas [Ni(NH3)6]2+ is an outer orbital complex.
[At. No.: Co = 27, Ni = 28]
Write the hybridisation and magnetic character of [Co(C2O4)3]3–.
(At. no. of Co = 27)
Write the hybridization type and magnetic behaviour of the complex [Ni(CN)4]2−. (Atomic number of Ni = 28)
Write the hybridization and magnetic character of the following complexes:
[Fe(CO)5]
(Atomic no. of Fe = 26)
Which of the following options are correct for \[\ce{[Fe(CN)6]^{3-}}\] complex?
(i) d2sp3 hybridisation
(ii) sp3d2 hybridisation
(iii) paramagnetic
(iv) diamagnetic
Magnetic moment of \[\ce{[MnCl4]^{2-}}\] is 5.92 BM. Explain giving reason.
Explain why \[\ce{[Fe(H2O)6]^{3+}}\] has magnetic moment value of 5.92 BM whereas \[\ce{[Fe(CN)6]^{3-}}\] – has a value of only 1.74 BM.
Why do compounds having similar geometry have different magnetic moment?
[Ti(H2O6]3+ T is paramagnetic is nature due to
The correct order of magnetic moment (spin only value in B.m.) is:
Low oxidation state of metals in their complexes are common when ligands ______.
Explain [Fe(CN)6]3− is an inner orbital complex, whereas [FeF6]3− is an outer orbital complex.
[Atomic number: Fe = 26]
