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प्रश्न
Explain [Fe(CN)6]3− is an inner orbital complex, whereas [FeF6]3− is an outer orbital complex.
[Atomic number: Fe = 26]
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उत्तर
[Fe(CN)6]3−
Fe = 3 oxidation state
i.e., electronic configuration = 3d5
CNΘ = strong field ligand
i.e., Δ0 > P pairing will take place
Electronic configuration of Fe3+ = 3d5
[FeF6]3−
Fe = +3 oxidation state
F− = Weak field ligand Δ0 < P `->` Pairing will not take place.
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संबंधित प्रश्न
For the complex [Fe(H2O)6]+3, write the hybridisation, magnetic character and spin of the complex. (At, number : Fe = 26)
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Reason: Because it has d2sp3 type hybridisation.
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