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प्रश्न
On the basis of crystal field theory, write the electronic configuration for the d5 ion with a weak ligand for which Δ0 < P.
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उत्तर
For weak field ligand Δ0 < P i.e., pairing will not occur for d5 ion.
संबंधित प्रश्न
How does the magnitude of Δ0 decide the actual configuration of d orbitals in a coordination entity?
Why are low spin tetrahedral complexes not formed?
Arrange following complex ions in increasing order of crystal field splitting energy (∆O):
\[\ce{[Cr(Cl)6]^{3-}, [Cr(CN)6]^{3-}, [Cr(NH3)6]^{3+}}\].
Why are different colours observed in octahedral and tetrahedral complexes for the same metal and same ligands?
In a coordination entity, the electronic configuration of the central metal ion is t2g3 eg1
Draw the crystal field splitting diagram for the above complex.
Considering crystal field theory, strong-field ligands such as CN–:
Crystal field stabilising energy for high spind4 octahedral complex is:-
For octahedral Mn(II) and tetrahedral Ni(II) complexes, consider the following statements:
- Both the complexes can be high spin.
- Ni(II) complex can very rarely below spin.
- With strong field Ligands, Mn(II) complexes can be low spin.
- Aqueous solution of Mn (II) ions is yellow in colour.
The correct statements are:
On the basis of Crystal Field Theory, write the electronic configuration of d4 ion if Δ0 > P.
The value of the spin only magnetic moment for one of the following configurations is 2.84 BM. The correct one is:
