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प्रश्न
How are the following conversions carried out?
Benzoic acid into metanitrobenzoic acid.
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उत्तर
Conversion of benzoic acid into meta-nitrobenzoic acid
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संबंधित प्रश्न
On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 > P.
State the superiority of crystal field theory over valence bond theory.
Why are low spin tetrahedral complexes rarely observed?
Atomic number of \[\ce{Mn}\], \[\ce{Fe}\] and \[\ce{Co}\] are 25, 26 and 27 respectively. Which of the following inner orbital octahedral complex ions are diamagnetic?
(i) \[\ce{[Co(NH3)6]^{3+}}\]
(ii) \[\ce{[Mn(CN)6]^{3-}}\]
(iii) \[\ce{[Fe(CN)6]^{4-}}\]
(iv) \[\ce{[Fe(CN)6]^{3-}}\]
On the basis of crystal field theory explain why Co(III) forms paramagnetic octahedral complex with weak field ligands whereas it forms diamagnetic octahedral complex with strong field ligands.
Arrange following complex ions in increasing order of crystal field splitting energy (∆O):
\[\ce{[Cr(Cl)6]^{3-}, [Cr(CN)6]^{3-}, [Cr(NH3)6]^{3+}}\].
Using crystal field theory, draw energy level diagram, write electronic configuration of the central metal atom/ion and determine the magnetic moment value in the following:
\[\ce{[CoF6]^{3-}, [Co(H2O)6]^{2+}, [Co(Cn)6]^{3-}}\]
Why are different colours observed in octahedral and tetrahedral complexes for the same metal and same ligands?
The CFSE for octahedral [CoCl6]−4 is 18,000 cm−1. What will be the CFSE for tetrahedral [CoCl3]−2?
[Ni(H2O)6]2+ (aq) is green in colour whereas [Ni(H2O)4 (en)]2+ (aq)is blue in colour, give reason in support of your answer.
In a coordination entity, the electronic configuration of the central metal ion is t2g3 eg1
Draw the crystal field splitting diagram for the above complex.
The correct order of increasing crystal field strength in following series:
The CFSE of [CoCl6]3– is 18000 cm–1 the CFSE for [CoCl4]– will be ______.
Using crystal field theory, write the electronic configuration of d5 ion, if Δ0 > P.
What is the difference between a weak field ligand and a strong field ligand?
The correct order of intensity of colors of the compounds is ______.
For octahedral Mn(II) and tetrahedral Ni(II) complexes, consider the following statements:
- Both the complexes can be high spin.
- Ni(II) complex can very rarely below spin.
- With strong field Ligands, Mn(II) complexes can be low spin.
- Aqueous solution of Mn (II) ions is yellow in colour.
The correct statements are:
Consider that d6 metal ion (M2+) forms a complex with aqua ligands and the spin only magnetic moment of the complex is 4.90 BM. The geometry and the crystal field stabilization energy of the complex are ______.
The complex that has highest crystal field splitting energy (Δ) is ______.
On the basis of Crystal Field theory, write the electronic configuration for the d5 ion with a strong field ligand for which Δ0 > P.
On the basis of crystal field theory, write the electronic configuration for the d5 ion with a weak ligand for which Δ0 < P.
Read the passage carefully and answer the questions that follow.
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Crystal field splitting by various ligands Metal complexes show different colours due to d-d transitions. The complex absorbs light of specific wavelength to promote the electron from t2g to eg level. The colour of the complex is due to the transmitted light, which is complementary of the colour absorbed. The wave number of light absorbed by different complexes of Cr ion are given below:
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Answer the following questions:
(a) Out of ligands "A", "B", "C" and "D", which ligand causes maximum crystal field splitting? Why?
OR
Which of the two, “A” or “D” will be a weak field ligand? Why?
(b) Which of the complexes will be violet in colour? [CrA6]3- or [CrB6]3+ and why?
(Given: If 560 - 570 nm of light is absorbed, the colour of the complex observed is violet.)
(c) If the ligands attached to Cr3+ ion in the complexes given in the table above are water, cyanide ion, chloride ion, and ammonia (not in this order).
Identify the ligand, write the formula and IUPAC name of the following:
- [CrA6]3-
- [CrC6]3+
On the basis of Crystal Field Theory, write the electronic configuration of d4 ion if Δ0 > P.
