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प्रश्न
Write the hybridization and shape of the following complexe : [Ni(CN)4]2–
(Atomic number : Co = 27, Ni = 28)
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उत्तर
The atomic number of Ni is 28 and its valence shell electronic configuration is 3d8 4s2.
Ni is in +2 oxidation state in the complex [Ni(CN)4]2–.
Hence, [Ni(CN)4]2– is dsp2 hybridised and it is square planar in shape.
संबंधित प्रश्न
For the complex [Fe(CN)6]3–, write the hybridization type, magnetic character and spin nature of the complex. (At. number : Fe = 26).
Write the hybridization and shape of the following complexe : [CoF6]3–
(Atomic number : Co = 27, Ni = 28)
Explain [Co(NH3)6]3+ is an inner orbital complex, whereas [Ni(NH3)6]2+ is an outer orbital complex.
[At. No.: Co = 27, Ni = 28]
Amongst the following ions, which one has the highest magnetic moment value?
Write the hybridisation and magnetic character of [Co(C2O4)3]3–.
(At. no. of Co = 27)
Write the hybridization and magnetic character of the following complexes:
[Fe(H2O)6]2+
(Atomic no. of Fe = 26)
Write the hybridization and magnetic character of the following complexes:
[Fe(CO)5]
(Atomic no. of Fe = 26)
Which of the following options are correct for \[\ce{[Fe(CN)6]^{3-}}\] complex?
(i) d2sp3 hybridisation
(ii) sp3d2 hybridisation
(iii) paramagnetic
(iv) diamagnetic
Magnetic moment of \[\ce{[MnCl4]^{2-}}\] is 5.92 BM. Explain giving reason.
Assertion: \[\ce{[Fe(CN)6]^{3-}}\] ion shows magnetic moment corresponding to two unpaired electrons.
Reason: Because it has d2sp3 type hybridisation.
