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प्रश्न
Write the hybridization and shape of the following complexe : [CoF6]3–
(Atomic number : Co = 27, Ni = 28)
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उत्तर
The atomic number of Co is 27 and its valence shell electronic configuration is 3d7 4s2.
Co is in +3 oxidation state in the complex [CoF6]3−.
Hence, [CoF6]3− is sp3d2 hybridised and it is octahedral in shape.
संबंधित प्रश्न
Write the hybridization and shape of the following complexe : [Ni(CN)4]2–
(Atomic number : Co = 27, Ni = 28)
[NiCl4]2− is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?
[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3− is weakly paramagnetic. Explain.
Amongst the following ions, which one has the highest magnetic moment value?
Which of the following options are correct for \[\ce{[Fe(CN)6]^{3-}}\] complex?
(i) d2sp3 hybridisation
(ii) sp3d2 hybridisation
(iii) paramagnetic
(iv) diamagnetic
Magnetic moment of \[\ce{[MnCl4]^{2-}}\] is 5.92 BM. Explain giving reason.
Explain why \[\ce{[Fe(H2O)6]^{3+}}\] has magnetic moment value of 5.92 BM whereas \[\ce{[Fe(CN)6]^{3-}}\] – has a value of only 1.74 BM.
Assertion: \[\ce{[Fe(CN)6]^{3-}}\] ion shows magnetic moment corresponding to two unpaired electrons.
Reason: Because it has d2sp3 type hybridisation.
[Ti(H2O6]3+ T is paramagnetic is nature due to
Given below are two statements:
Statement I: Ferromagnetism is considered as an extreme form of paramagnetism.
Statement II: The number of unpaired electrons in a Cr2+ ion (Z = 24) is the same as that of a Nd3+ ion (Z = 60).
In the light of the above statements, choose the correct answer from the options given below:
