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प्रश्न
Write balanced chemical equations for action of ammonia on - formaldehyde
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उत्तर
a. 6HCHO + 4NH3 → (CH2)6N4 + 6H2O
Formaldehyde Urotropine
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संबंधित प्रश्न
Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?
(A) Ammonia
(B) Hydroxylamine
(C) Ammoniacal silver nitrate
(D) Semicarbazide
How are the following compounds prepared?
benzaldehyde from benzene
Predict the products of the following reactions:
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
Hint: Consider steric effect and electronic effect.
What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
Semicarbazide and weak acid
Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
Give plausible explanation for the following:
Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
Write balanced chemical equations for action of ammonia on - acetaldehyde
Write balanced chemical equations for action of ammonia on - acetone
What is the action of the following reagents on ethanoic acid?
1) `LiAlH_4"/"H_3O^+`
2) `PCl_3 , "heat"`
3) `P_2O_5, "heat"`
How will you convert sodium acetate to methane?
Write the main product formed when propanal reacts with the following reagents:
H2N- NH2 followed by heating with KOH in ethylene glycol.
Which of the following compounds is most reactive towards nucleophilic addition reactions?
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
Paraldehyde is formed as a result of polymerisation:-
Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
The product "P" in the above reaction is:
The increasing order of the following compounds towards HCN addition is:
| (i) |  |
| (ii) |  |
| (iii) |  |
| (iv) |  |
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Why dissociation of HCN is suppressed by the addition of HCL?
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative:
Acetaldehydedimethylacetal
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Oxime
