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प्रश्न
How are the following compounds prepared?
acetophenone from benzene
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उत्तर
(b)Acetophenone from benzene
Friedal craft reaction
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संबंधित प्रश्न
Predict the product of the following reaction:
Predict the product of the following reaction:
\[\begin{array}{cc}
\phantom{..............}\ce{O}\\
\phantom{..............}||\\
\ce{R - CH = CH - CHO + NH2 - C - NH - NH2 ->[H+]}\end{array}\]
What is meant by the following term? Give an example of the reaction in the following case.
Cyanohydrin
What is meant by the following term? Give an example of the reaction in the following case.
Imine
What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
PhMgBr and then H3O+
Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
Complete the synthesis by giving missing starting material, reagent or product.
\[\ce{C6H5CHO ->[H2NCONHNH2]}\]
Write balanced chemical equations for action of ammonia on - acetone
What is the action of the following reagents on ethanoic acid?
1) `LiAlH_4"/"H_3O^+`
2) `PCl_3 , "heat"`
3) `P_2O_5, "heat"`
Give a simple chemical test to distinguish between 
Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN.
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?
Identify the compounds A, B and C in the following reaction.
\[\ce{CH3 - Br ->[Mg/ether] (A) ->[(i) CO][(ii) Water] (B) ->[CH3OH/H+][Δ] (C)}\]
Acetaldehyde and acetone differ in their reaction with
Which among the following is most reactive to give nucleophilic addition?
Arrange the following in the increasing order of their property indicated:
Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)
The product of following reaction is
\[\ce{CH3 - CH = CH - CH2 - CHO ->[i) LiAlH4][ii) H3O+]}\] ______?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Out of p-tolualdehyde and p-nitrobenzaldehyde, which one is more reactive towards nucleophilic addition reactions, why?
Draw the structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structures of the following derivatives.
Acetaldehydedimethylacetal
