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प्रश्न
How are the following compounds prepared?
acetophenone from benzene
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उत्तर
(b)Acetophenone from benzene
Friedal craft reaction
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संबंधित प्रश्न
Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:
C6H5COCH3, CH3-CHO, CH3COCH3
Draw the structure of the semicarbazone of ethanal.
Write the structures of the main products when acetone (CH3 − CO − CH3) reacts with the following reagent :
H2N − NHCONH2/H+
Predict the product of the following reaction:
\[\begin{array}{cc}
\phantom{..............}\ce{O}\\
\phantom{..............}||\\
\ce{R - CH = CH - CHO + NH2 - C - NH - NH2 ->[H+]}\end{array}\]
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
Give plausible explanation for the following:
Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
Explain the mechanism of alkaline hydrolysis of tert-butyl bromide with energy profile diagram.
Write the structure of Phenylmethanamine.
Which of the following compounds is most reactive towards nucleophilic addition reactions?
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
Benzaldehyde can be obtained from benzal chloride. Write reactions for obtaining benzalchloride and then benzaldehyde from it.
Alkenes 
and carbonyl compounds 
, both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.
Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?
Identify the compounds A, B and C in the following reaction.
\[\ce{CH3 - Br ->[Mg/ether] (A) ->[(i) CO][(ii) Water] (B) ->[CH3OH/H+][Δ] (C)}\]
The pH of blood does not appreciably change by a small addition of acid or base because
Paraldehyde is formed as a result of polymerisation:-
Which among the following is most reactive to give nucleophilic addition?
Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
What is the action of sodium hypoiodite on acetone?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw structure of the following derivative.
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the given derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Oxime
