Advertisements
Advertisements
Question
How are the following compounds prepared?
acetophenone from benzene
Advertisements
Solution
(b)Acetophenone from benzene
Friedal craft reaction
APPEARS IN
RELATED QUESTIONS
Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?
(A) Ammonia
(B) Hydroxylamine
(C) Ammoniacal silver nitrate
(D) Semicarbazide
How are the following compounds prepared?
benzaldehyde from benzene
Write the products formed when CH3CHO reacts with the following reagents : H2N – OH
What is meant by the following term? Give an example of the reaction in the following case.
Ketal
What is meant by the following term? Give an example of the reaction in the following case.
Schiff’s base
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
PhMgBr and then H3O+
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
Semicarbazide and weak acid
Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
Give plausible explanation for the following:
Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
Give plausible explanation for the following:
There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
Complete the synthesis by giving missing starting material, reagent or product.
Write balanced chemical equations for action of ammonia on - acetone
Write the main product formed when propanal reacts with the following reagents:
H2N- NH2 followed by heating with KOH in ethylene glycol.
The pH of blood does not appreciably change by a small addition of acid or base because
Acetaldehyde and acetone differ in their reaction with
Which will undergo faster nucleophilic addition reaction?
Acetaldehyde or Propanone
In the following reaction
\[\ce{Carbonyl compound + MeOH <=>[HCl] acetal}\]
Rate of the reaction is the highest for ______.
Which of the following is most reactive in nucleophilic addition reactions?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw structure of the following derivative:
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
