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प्रश्न
Write any four applications of buffer solution.
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उत्तर
Buffer solution finds extensive applications in a variety of fields. Some of its applications are given.
- In a biochemical system: pH of blood in our body is maintained at 7.36 - 7.42 due to \[\ce{(HCO^-3 + H2CO3)}\] buffer. A mere change of 0.2 pH units can cause death. The saline solution used for intravenous injection must contain a buffer system to maintain the proper pH of the blood.
- Agriculture: The soils get buffered due to the presence of salts such as carbonate, bicarbonate, phosphates, and organic acids. The choice of fertilizers depends upon the pH of the soil.
- Industry: Buffers play an important role in the paper, dye, ink, paint, and drug industries.
- Medicine: Penicillin preparations are stabilized by the addition of sodium citrate as a buffer. When citric acid is added to milk of magnesia (Mg(OH)2), magnesium citrate is formed, which is a buffer.
- Analytical chemistry: In qualitative analysis, a pH of 8 to 10 is required for precipitation of cations IIIA group. It is maintained with the use of (NH4OH + NH4Cl) buffer.
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When NH4 Cl and NH4OH are added to a solution containing both, Fe3+ and Ca2+ ions, which ion is precipitated first and why?
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Classify the following buffers into different types :
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The pKb of weak base BOH [Kb(BOH) = 1 × 10-5] will be ______.
Name the buffer which is used to maintained pH of 8 to 10 for precipitation of cations III A group in qualitative analysis.
Write the formula to calculate pH of buffer solution.
Define buffer solution.
Explain the types of buffer solutions.
A buffer solution contains 0.3 mol dm–3 NH4OH (Kb = 1.8 × 10–5) and 0.4 mol dm–3 NH4Cl. Calculate pOH of the solution.
Veronal is used as a/an ______.
____________ forms a basic buffer solution.
On the basis of the equation \[\ce{pH}\] = – log \[\ce{[H+]}\], the \[\ce{pH}\] of 10–8 mol dm–3 solution of \[\ce{HCl}\] should be 8. However, it is observed to be less than 7.0. Explain the reason.
Assertion (A): An aqueous solution of ammonium acetate can act as a buffer.
Reason (R): Acetic acid is a weak acid and \[\ce{NH4OH}\] is a weak base.
Calculate the pH of buffer solution composed of 0.01 M weak base BOH and 0.02 M of its salt BA. [Kb = 1.8 × 10–5 for weak base]
Explain buffer action of sodium acetate-acetic acid buffer.
Calculate the pOH of a buffer solution formed from 0.3 M weak base and 0.45 M of its salt with strong acid [pKb = 4.7447].
A buffer solution is prepared by mixing 0.01 М HCN and 0.02 M sodium cyanide. If pKa for HCN is 5.20, what is the pH of solution?
