Advertisements
Advertisements
प्रश्न
Calculate the pH of buffer solution composed of 0.01 M weak base BOH and 0.02 M of its salt BA. [Kb = 1.8 × 10–5 for weak base]
Advertisements
उत्तर
pOH = pKb + log10 `(["Salt"])/(["Base"])`
Now, pKb = – log10 Kb
= 5 – log101.8
= 5 – 0.2553
pKb = 4.7447
Then, pOH = 4.7447 + log10 `0.02/0.01`
= 4.7447 + log102
= 4.7447 + 0.3010
pOH = 5.0457
∵ pH + pOH = 14
∴ pH = 14 – pOH
= 14 – 5.0457
= 8.9543 or 8.9
pH = 8.95
The pH of the buffer solution will be 8.95.
APPEARS IN
संबंधित प्रश्न
When NH4 Cl and NH4OH are added to a solution containing both, Fe3+ and Ca2+ ions, which ion is precipitated first and why?
Cu is precipitated as CuS while Zn is not precipitated when H2S is passed through an acidic solution of Cu(NO3 )2 and Zn(NO3)2 respectively.
Choose the most correct answer:
Which of the Na following is a buffer solution?
Answer the following in one sentence :
How are basic buffer solutions prepared?
Answer the following in one sentence :
Write one property of a buffer solution.
Answer the following in one sentence :
Classify the following buffers into different types :
CH3COOH + CH3COONa
Answer the following in one sentence :
Classify the following buffers into different types :
NH4OH + NH4Cl
Answer the following in one sentence :
Classify the following buffers into different types :
Sodium benzoate + benzoic acid
Write the formula to calculate pH of buffer solution.
Explain the types of buffer solutions.
Write one application of the following buffer:
Citrate buffer
What is the pH of 0.5 litre buffer solution containing 0.01 mole of CH3COOH and 0.01 mole of CH3COONa?
[pKa of acid = 4.74]
The dissociation constant of a weak acid is 1 × 10−3. In order to prepare a buffer solution with a pH = 4, the `(["Acid"])/(["Salt"])` ratio should be ____________.
Ksp of Al(OH)3 is 1 × 10−15 M. At what pH does 1.0 × 10−3 M Al3+ precipitate on the addition of buffer of NH4Cl and NH4OH solution?
Which of the following will produce a buffer solution when mixed in equal volumes?
On the basis of the equation \[\ce{pH}\] = – log \[\ce{[H+]}\], the \[\ce{pH}\] of 10–8 mol dm–3 solution of \[\ce{HCl}\] should be 8. However, it is observed to be less than 7.0. Explain the reason.
Assertion (A): A solution containing a mixture of acetic acid and sodium acetate maintains a constant value of \[\ce{pH}\] on addition of small amounts of acid or alkali.
Reason (R): A solution containing a mixture of acetic acid and sodium acetate acts as a buffer solution around \[\ce{pH}\] 4.75.
Which of the following combinations will constitute a buffer solution?
Define Acidic buffer solution.
Write any four applications of buffer solution.
Explain buffer action of sodium acetate-acetic acid buffer.
Calculate the pOH of a buffer solution formed from 0.3 M weak base and 0.45 M of its salt with strong acid [pKb = 4.7447].
A buffer solution is prepared by mixing 0.1 M ammonia solution and 0.25 M solution of NH4CI. What is the value of pKb to maintain its pOH at 6?
