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प्रश्न
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
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उत्तर
Lead is known not to form PbI4. Pb (+4) is oxidising in nature and I- is reducing in nature. A combination of Pb(IV) and iodide ion is not stable. Iodide ion is strongly reducing in nature. Pb(IV) oxidises I– to I2 and itself gets reduced to Pb(II).
\[\ce{PbI_4 -> PbI_2 + I_2}\]
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of B to Tl.
Discuss the pattern of variation in the oxidation states of C to Pb.
Explain the difference in properties of diamond and graphite on the basis of their structures.
Rationalise the given statement and give a chemical reaction:
Lead (II) chloride reacts with Cl2 to give PbCl4.
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Elements of group 14 ________.
Classify the following oxide as neutral, acidic, basic or amphoteric:
SiO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Al2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Tl2O3
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Which of the following is a Lewis acid?
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
Why does the element silicon, not form a graphite like structure whereas carbon does.
A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
\[\ce{SiCl4 ->[H2O] (A) ->[\Delta] (B) ->[Na2CO3][heat] (C)}\]. The Compound C is ______.
Match List I with List II:
| List I | List II |
| Coke | Carbon atoms are sp3 hybridized. |
| Diamond | Used as a dry lubricant. |
| Fullerene | Used as a reducing agent. |
| Graphite | Cage like molecules |
Choose the correct answer from the options given below:
