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प्रश्न
Elements of group 14 ________.
विकल्प
exhibit oxidation state of +4 only
exhibit oxidation state of +2 and +4
form M2– and M4+ ions
form M2+ and M4+ ions
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उत्तर
Elements of group 14 exhibit oxidation state of +2 and +4.
Explanation:
The elements of group 14 have 4 valence electrons. Therefore, the oxidation state of the group is +4. However, as a result of the inert pair effect, the lower oxidation state becomes more and more stable and the higher oxidation state becomes less stable. Therefore, this group exhibits +4 and +2 oxidation states
| Group 14 element | Oxidation state |
| C | +4 |
| Si | +4 |
| Ge, Sn, Pb | +2, +4 |
संबंधित प्रश्न
Rationalise the given statement and give a chemical reaction:
Lead (II) chloride reacts with Cl2 to give PbCl4.
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
Classify the following oxide as neutral, acidic, basic or amphoteric:
B2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
SiO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Al2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Tl2O3
Write suitable chemical equations to show the nature of the following oxide.
SiO2
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Which of the following is a Lewis acid?
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order:
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
\[\ce{SiCl4 ->[H2O] (A) ->[\Delta] (B) ->[Na2CO3][heat] (C)}\]. The Compound C is ______.
Match List I with List II:
| List I | List II |
| Coke | Carbon atoms are sp3 hybridized. |
| Diamond | Used as a dry lubricant. |
| Fullerene | Used as a reducing agent. |
| Graphite | Cage like molecules |
Choose the correct answer from the options given below:
