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प्रश्न
Rationalise the given statement and give a chemical reaction:
Lead (II) chloride reacts with Cl2 to give PbCl4.
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उत्तर
Lead belongs to group 14 of the periodic table. The two oxidation states displayed by this group is +2 and +4. On moving down the group, the +2 oxidation state becomes more stable and the +4 oxidation state becomes less stable. This is because of the inert pair effect. Hence, PbCl4 is much less stable than PbCl2. However, the formation of PbCl4 takes place when chlorine gas is bubbled through a saturated solution of PlCl2.
\[\ce{PbCl_{2(s)} + Cl_{2(g)} -> PbCl_{4(l)}}\]
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of B to Tl.
Explain the difference in properties of diamond and graphite on the basis of their structures.
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Elements of group 14 ________.
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO
Classify the following oxide as neutral, acidic, basic or amphoteric:
B2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
SiO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Al2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Write suitable chemical equations to show the nature of the following oxide.
CO2
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Explain the following:
CO2 is a gas whereas SiO2 is a solid.
The +1 oxidation state in group 13 and +2 oxidation state in group 14 becomes more and more stable with increasing atomic number. Explain.
Explain the following:
Why does the element silicon, not form a graphite like structure whereas carbon does.
Match List I with List II:
| List I | List II |
| Coke | Carbon atoms are sp3 hybridized. |
| Diamond | Used as a dry lubricant. |
| Fullerene | Used as a reducing agent. |
| Graphite | Cage like molecules |
Choose the correct answer from the options given below:
