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प्रश्न
Elements of group 14 ________.
पर्याय
exhibit oxidation state of +4 only
exhibit oxidation state of +2 and +4
form M2– and M4+ ions
form M2+ and M4+ ions
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उत्तर
Elements of group 14 exhibit oxidation state of +2 and +4.
Explanation:
The elements of group 14 have 4 valence electrons. Therefore, the oxidation state of the group is +4. However, as a result of the inert pair effect, the lower oxidation state becomes more and more stable and the higher oxidation state becomes less stable. Therefore, this group exhibits +4 and +2 oxidation states
| Group 14 element | Oxidation state |
| C | +4 |
| Si | +4 |
| Ge, Sn, Pb | +2, +4 |
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of C to Pb.
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
Classify the following oxide as neutral, acidic, basic or amphoteric:
B2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
SiO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Al2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Write suitable chemical equations to show the nature of the following oxide.
SiO2
Write suitable chemical equations to show the nature of the following oxide.
CO2
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
Which of the following is a Lewis acid?
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Give reasons for the following:
CCl4 is immiscible in water, whereas SiCl4 is easily hydrolysed.
Carbon and silicon both belong to the group 14, but inspite of the stoichiometric similarity, the dioxides, (i.e., carbon dioxide and silicon dioxide), differ in their structures. Comment.
Explain the following:
Carbon shows catenation property but lead does not.
Explain the following:
BF3 does not hydrolyse.
The principal ore of lead is ______.
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
