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The reason for small radius of Ga compared to Al is: (i) poor screening effect of d and f orbitals. (ii) increase in nuclear charge. (iii) presence of higher orbitals. (iv) higher atomic number.

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प्रश्न

The reason for small radius of Ga compared to Al is:

(i) poor screening effect of d and f orbitals.

(ii) increase in nuclear charge.

(iii) presence of higher orbitals.

(iv) higher atomic number.

टीपा लिहा
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उत्तर

(i) poor screening effect of d and f orbitals.

(ii) increase in nuclear charge.

Explanation:

The additional 10 d-electrons offer poor screening effect for the outer electrons from the increased fluclear charge in Gallium. Hence, atomic radius of Gallium is less than that of aluminium.

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पाठ 11: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३६]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 16 | पृष्ठ १३६

संबंधित प्रश्‍न

Discuss the pattern of variation in the oxidation states of  B to Tl.


Discuss the pattern of variation in the oxidation states of C to Pb.


Explain the difference in properties of diamond and graphite on the basis of their structures.


Rationalise the given statement and give a chemical reaction:

Lead (II) chloride reacts with Cl2 to give PbCl4.


Explain the following reaction.

Silicon is heated with methyl chloride at high temperature in the presence of copper.


Rationalise the given statement and give a chemical reaction:

Lead (IV) chloride is highly unstable towards heat.


Classify the following oxide as neutral, acidic, basic or amphoteric:

CO


Classify the following oxide as neutral, acidic, basic or amphoteric:

B2O3


Write suitable chemical equations to show the nature of the following oxide.

B2O3


Write suitable chemical equations to show the nature of the following oxide.

SiO2


The linear shape of CO2 is due to:

(i) sp3 hybridisation of carbon.

(ii) sp hybridisation of carbon.

(iii) pπ – pπ bonding between carbon and oxygen.

(iv) sp2 hybridisation of carbon.


Explain the following:

CO2 is a gas whereas SiO2 is a solid.


Explain the following:

Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.


Carbon and silicon both belong to the group 14, but inspite of the stoichiometric similarity, the dioxides, (i.e., carbon dioxide and silicon dioxide), differ in their structures. Comment.


\[\ce{SiCl4 ->[H2O] (A) ->[\Delta] (B) ->[Na2CO3][heat] (C)}\]. The Compound C is ______.


Which one of the following compounds of Group–14 elements is not known?


Match List I with List II:

List I List II
Coke Carbon atoms are sp3 hybridized.
Diamond Used as a dry lubricant.
Fullerene Used as a reducing agent.
Graphite Cage like molecules

Choose the correct answer from the options given below:


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