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A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent

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प्रश्न

A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.

दीर्घउत्तर
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उत्तर

\[\ce{2C (s) + O2 + 4N2 (g) ->[123 k] 2CO (g) + 4N2 (g)}\]

\[\ce{Fe2O3 (S) + 3CO (g) ->[heat] 2Fe (S) + 3CO2}\]

C = tetravalent carbon 

CO = carbon monoxide 

Fe2O3 = ferric oxide 

CO2 = carbon dioxide

Tetravalent elements i.e. carbon combines with oxygen to produce carbon monoxide. The reaction occurs at high temperatures and in the presence of nitrogen gas, which acts as a producer gas only. It is not consumed in the reaction. The carbon monoxide formed acts as a reducing agent for ferric oxide, reduces the oxidation state of iron from +3 to zero, and oxidizes itself to form carbon dioxide.

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पाठ 11: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १४१]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 50 | पृष्ठ १४१

संबंधित प्रश्‍न

Explain the difference in properties of diamond and graphite on the basis of their structures.


Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?


Write suitable chemical equations to show the nature of the following oxide.

Tl2O3


Rationalise the given statement and give a chemical reaction:

Lead (IV) chloride is highly unstable towards heat.


Rationalise the given statement and give a chemical reaction:

Lead is known not to form an iodide, PbI4.


Classify the following oxide as neutral, acidic, basic or amphoteric:

PbO2


Classify the following oxide as neutral, acidic, basic or amphoteric:

Tl2O3


Write suitable chemical equations to show the nature of the following oxide.

B2O3


Write suitable chemical equations to show the nature of the following oxide.

PbO2


The reason for small radius of Ga compared to Al is:

(i) poor screening effect of d and f orbitals.

(ii) increase in nuclear charge.

(iii) presence of higher orbitals.

(iv) higher atomic number.


The linear shape of CO2 is due to:

(i) sp3 hybridisation of carbon.

(ii) sp hybridisation of carbon.

(iii) pπ – pπ bonding between carbon and oxygen.

(iv) sp2 hybridisation of carbon.


Explain the following:

Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.


Explain the following:

Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.


Carbon and silicon both belong to the group 14, but inspite of the stoichiometric similarity, the dioxides, (i.e., carbon dioxide and silicon dioxide), differ in their structures. Comment.


The principal ore of lead is ______. 


\[\ce{SiCl4 ->[H2O] (A) ->[\Delta] (B) ->[Na2CO3][heat] (C)}\]. The Compound C is ______.


Which one of the following compounds of Group–14 elements is not known?


Match List I with List II:

List I List II
Coke Carbon atoms are sp3 hybridized.
Diamond Used as a dry lubricant.
Fullerene Used as a reducing agent.
Graphite Cage like molecules

Choose the correct answer from the options given below:


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