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प्रश्न
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
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उत्तर
Ionisation enthalpy of carbon (the first element of group 14) is very high (1086 kJ/mol). This is expected owing to its small size. However, on moving down the group to silicon, there is a sharp decrease in the enthalpy (786 kJ). This is because of an appreciable increase in the atomic sizes of elements on moving down the group.
संबंधित प्रश्न
Explain the following reaction.
Silicon is heated with methyl chloride at high temperature in the presence of copper.
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Al2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
Tl2O3
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
Write suitable chemical equations to show the nature of the following oxide.
PbO2
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Explain the following:
CO2 is a gas whereas SiO2 is a solid.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
The +1 oxidation state in group 13 and +2 oxidation state in group 14 becomes more and more stable with increasing atomic number. Explain.
Carbon and silicon both belong to the group 14, but inspite of the stoichiometric similarity, the dioxides, (i.e., carbon dioxide and silicon dioxide), differ in their structures. Comment.
Explain the following:
Carbon shows catenation property but lead does not.
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
Which one of the following compounds of Group–14 elements is not known?
