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प्रश्न
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
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उत्तर
Ionisation enthalpy of carbon (the first element of group 14) is very high (1086 kJ/mol). This is expected owing to its small size. However, on moving down the group to silicon, there is a sharp decrease in the enthalpy (786 kJ). This is because of an appreciable increase in the atomic sizes of elements on moving down the group.
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of B to Tl.
Rationalise the given statement and give a chemical reaction:
Lead (II) chloride reacts with Cl2 to give PbCl4.
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Tl2O3
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Write suitable chemical equations to show the nature of the following oxide.
SiO2
Write suitable chemical equations to show the nature of the following oxide.
CO2
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Which of the following is a Lewis acid?
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Carbon and silicon both belong to the group 14, but inspite of the stoichiometric similarity, the dioxides, (i.e., carbon dioxide and silicon dioxide), differ in their structures. Comment.
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
