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प्रश्न
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
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उत्तर
On moving down group IV, the higher oxidation state becomes unstable because of the inert pair effect. Pb(IV) is highly unstable and when heated, it reduces to Pb (II).
\[\ce{PbCl_{4(l)} ->[\Delta] PbCl_{2(s)} + Cl_{2(g)}}\]
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of B to Tl.
Discuss the pattern of variation in the oxidation states of C to Pb.
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Tl2O3
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Write suitable chemical equations to show the nature of the following oxide.
SiO2
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order:
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
Give reasons for the following:
CCl4 is immiscible in water, whereas SiCl4 is easily hydrolysed.
Explain the following:
Carbon shows catenation property but lead does not.
A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.
The principal ore of lead is ______.
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
