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प्रश्न
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
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उत्तर
On moving down group IV, the higher oxidation state becomes unstable because of the inert pair effect. Pb(IV) is highly unstable and when heated, it reduces to Pb (II).
\[\ce{PbCl_{4(l)} ->[\Delta] PbCl_{2(s)} + Cl_{2(g)}}\]
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of B to Tl.
Explain the difference in properties of diamond and graphite on the basis of their structures.
Explain the following reaction.
Silicon is heated with methyl chloride at high temperature in the presence of copper.
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
Classify the following oxide as neutral, acidic, basic or amphoteric:
B2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO2
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order:
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Explain the following:
Why does the element silicon, not form a graphite like structure whereas carbon does.
A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.
The principal ore of lead is ______.
\[\ce{SiCl4 ->[H2O] (A) ->[\Delta] (B) ->[Na2CO3][heat] (C)}\]. The Compound C is ______.
Match List I with List II:
| List I | List II |
| Coke | Carbon atoms are sp3 hybridized. |
| Diamond | Used as a dry lubricant. |
| Fullerene | Used as a reducing agent. |
| Graphite | Cage like molecules |
Choose the correct answer from the options given below:
