Advertisements
Advertisements
Question
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
Advertisements
Solution
On moving down group IV, the higher oxidation state becomes unstable because of the inert pair effect. Pb(IV) is highly unstable and when heated, it reduces to Pb (II).
\[\ce{PbCl_{4(l)} ->[\Delta] PbCl_{2(s)} + Cl_{2(g)}}\]
RELATED QUESTIONS
Discuss the pattern of variation in the oxidation states of C to Pb.
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
Classify the following oxide as neutral, acidic, basic or amphoteric:
Al2O3
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Which of the following is a Lewis acid?
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order:
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Explain the following:
CO2 is a gas whereas SiO2 is a solid.
Explain the following:
Carbon shows catenation property but lead does not.
Explain the following:
BF3 does not hydrolyse.
A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.
\[\ce{SiCl4 ->[H2O] (A) ->[\Delta] (B) ->[Na2CO3][heat] (C)}\]. The Compound C is ______.
