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Karnataka Board PUCPUC Science Class 11

Rationalise the given statement and give a chemical reaction: Lead (IV) chloride is highly unstable towards heat.

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Question

Rationalise the given statement and give a chemical reaction:

Lead (IV) chloride is highly unstable towards heat.

Short/Brief Note
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Solution

On moving down group IV, the higher oxidation state becomes unstable because of the inert pair effect. Pb(IV) is highly unstable and when heated, it reduces to Pb (II).
\[\ce{PbCl_{4(l)} ->[\Delta] PbCl_{2(s)} + Cl_{2(g)}}\]

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