Advertisements
Advertisements
Question
Explain the following reaction.
Silicon is heated with methyl chloride at high temperature in the presence of copper.
Advertisements
Solution
When silicon reacts with methyl chloride in the presence of copper (catalyst) and at a temperature of about 537 K, a class of organosilicon polymers called methyl-substituted chlorosilanes (MeSiCl3, Me2SiCl2, Me3SiCl, and Me4Si) are formed
RELATED QUESTIONS
Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO
Classify the following oxide as neutral, acidic, basic or amphoteric:
SiO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Tl2O3
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Write suitable chemical equations to show the nature of the following oxide.
SiO2
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order:
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
Give reasons for the following:
CCl4 is immiscible in water, whereas SiCl4 is easily hydrolysed.
Explain the following:
CO2 is a gas whereas SiO2 is a solid.
The +1 oxidation state in group 13 and +2 oxidation state in group 14 becomes more and more stable with increasing atomic number. Explain.
Explain the following:
Why does the element silicon, not form a graphite like structure whereas carbon does.
The principal ore of lead is ______.
Which one of the following compounds of Group–14 elements is not known?
