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प्रश्न
Explain the following reaction.
Silicon is heated with methyl chloride at high temperature in the presence of copper.
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उत्तर
When silicon reacts with methyl chloride in the presence of copper (catalyst) and at a temperature of about 537 K, a class of organosilicon polymers called methyl-substituted chlorosilanes (MeSiCl3, Me2SiCl2, Me3SiCl, and Me4Si) are formed
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of B to Tl.
Discuss the pattern of variation in the oxidation states of C to Pb.
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
Classify the following oxide as neutral, acidic, basic or amphoteric:
SiO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO2
Classify the following oxide as neutral, acidic, basic or amphoteric:
Tl2O3
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Write suitable chemical equations to show the nature of the following oxide.
CO2
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Which of the following is a Lewis acid?
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order:
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
The +1 oxidation state in group 13 and +2 oxidation state in group 14 becomes more and more stable with increasing atomic number. Explain.
Carbon and silicon both belong to the group 14, but inspite of the stoichiometric similarity, the dioxides, (i.e., carbon dioxide and silicon dioxide), differ in their structures. Comment.
Explain the following:
BF3 does not hydrolyse.
A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.
