Advertisements
Advertisements
Question
Explain the following:
CO2 is a gas whereas SiO2 is a solid.
Advertisements
Solution
Because of its small size and good π-overlap with other small atoms, carbon forms strong double bonds with two oxygen atoms to give discrete CO2 molecules.
Silicon atom, on account of large size, does not have good π-overlap with other atoms. It uses its four valence electrons to form four single bonds directed towards the four apices of a tetrahedron (sp3-hybridisation). Each oxygen is linked with two silicon atoms, i.e., a giant three-dimensional structure comes into existence which is very stable. Thus, CO2 is a gas and SiO2 is a solid.
\[\ce{O = C = O}\]
APPEARS IN
RELATED QUESTIONS
Explain the difference in properties of diamond and graphite on the basis of their structures.
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO
Classify the following oxide as neutral, acidic, basic or amphoteric:
B2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
SiO2
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Write suitable chemical equations to show the nature of the following oxide.
CO2
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
Write suitable chemical equations to show the nature of the following oxide.
PbO2
Which of the following is a Lewis acid?
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
Give reasons for the following:
CCl4 is immiscible in water, whereas SiCl4 is easily hydrolysed.
The +1 oxidation state in group 13 and +2 oxidation state in group 14 becomes more and more stable with increasing atomic number. Explain.
Explain the following:
BF3 does not hydrolyse.
Explain the following:
Why does the element silicon, not form a graphite like structure whereas carbon does.
A tetravalent element forms monoxide and dioxide with oxygen. When air is passed over heated element (1273 K), producer gas is obtained. Monoxide of the element is a powerful reducing agent and reduces ferric oxide to iron. Identify the element and write formulas of its monoxide and dioxide. Write chemical equations for the formation of producer gas and reduction of ferric oxide with the monoxide.
