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Karnataka Board PUCPUC Science Class 11

Rationalise the given statement and give a chemical reaction: Lead is known not to form an iodide, PbI4.

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Question

Rationalise the given statement and give a chemical reaction:

Lead is known not to form an iodide, PbI4.

Short/Brief Note
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Solution

Lead is known not to form PbI4. Pb (+4) is oxidising in nature and I- is reducing in nature. A combination of Pb(IV) and iodide ion is not stable. Iodide ion is strongly reducing in nature. Pb(IV) oxidises I to I2 and itself gets reduced to Pb(II).

\[\ce{PbI_4 -> PbI_2 + I_2}\]

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