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Out of Mn3+ and Cr3+, which is more paramagnetic and why ?
(Atomic nos. : Mn = 25, Cr = 24)
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Why is adsorption always exothermic?
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Give the significance of a ‘lattice point’.
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Name the parameters that characterize a unit cell.
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Which of the following lattices has the highest packing efficiency (i) simple cubic (ii) body-centred cubic and (iii) hexagonal close-packed lattice?
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What is meant by the term ‘coordination number’?
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How would you determine the standard electrode potential of the system Mg2+ | Mg?
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Consult the table of standard electrode potentials and suggest three substances that can oxidise ferrous ions under suitable conditions.
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Calculate the standard cell potential of a galvanic cell in which the following reaction takes place:
\[\ce{2Cr_{(s)} + 3Cd{^{2+}_{(aq)}} -> 2Cr{^{3+}_{(aq)}} + 3Cd_{(s)}}\]
Calculate the ΔrG° and equilibrium constant of the reaction.
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Write any two characteristics of chemisorption.
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Why are powdered substances more effective adsorbents than their crystalline forms?
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Distinguish between the meaning of the terms adsorption and absorption. Give one example of.
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What is the difference between physisorption and chemisorption?
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Give reason why a finely divided substance is more effective as an adsorbent.
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What are the factors which influence the adsorption of a gas on a solid?
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Discuss the effect of temperature on the adsorption of gases on solids.
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In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?
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Which of the 3d series of the transition metals exhibits the largest number of oxidation states and why?
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The \[\ce{E^{\circ}_{(M^{2+}/M)}}\] value for copper is positive (+0.34 V). What is possible reason for this? (Hint: consider its high ΔaH° and low ΔhydH°)
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