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Question
How can phenol be converted to aspirin?
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Solution

2-hydroxybenzoic acid on treatment with acetic anhydride will give asprin.
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RELATED QUESTIONS
Name the following compound according to the IUPAC system.
\[\begin{array}{cc}
\phantom{.....................................}\ce{CH2OH}\\
\phantom{............................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
|\phantom{....................}|\phantom{............}\\
\ce{CH3}\phantom{..............}\ce{OH}\phantom{.........}\\
\end{array}\]
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{.........}|\phantom{...}\\
\ce{OH}\phantom{....}\ce{OH}\\
\end{array}\]
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\[\begin{array}{cc}
\ce{HO - CH2 - CH - CH2 - OH}\\
|\phantom{...}\\
\ce{OH}\phantom{.}\\
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{................}|\\
\phantom{....................}\ce{CH3}
\end{array}\]
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Cresol has ____________.
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\ce{CH3 - CH - OCH3}\\
\phantom{}|\phantom{....}\\
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\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
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Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.
| Column I | Column II | ||
| (i) | CH3—O—CH3 | (a) | ![]() |
| (ii) | \[\begin{array}{cc} \ce{CH3}\phantom{..................}\\ \backslash\phantom{.............}\\ \ce{CH-O-CH3}\\ /\phantom{..............}\\ \ce{CH3}\phantom{..................} \end{array}\] |
(b) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-I + CH3OH}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
| (iii) | \[\begin{array}{cc} \ce{CH3}\phantom{.}\\ |\phantom{....}\\ \ce{H3C-C-O-CH3}\\ |\phantom{....}\\ \ce{CH3}\phantom{..} \end{array}\] |
(c) | ![]() |
| (iv) | ![]() |
(d) | CH3—OH + CH3—I |
| (e) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-OH + CH3I}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
| (f) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-I + CH3OH}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
| (g) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-OH + CH3I}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.
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