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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chloromethane on treatment with excess of ammonia yields mainly ______.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Why iodoform has appreciable antiseptic property?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

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Name the alkene which will yield 1-chloro-1-methylcyclohexane by its reaction with \[\ce{HCl}\]. Write the reactions involved.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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Diphenyls are potential threat to the environment. How are these produced from arylhalides?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

What are the IUPAC names of the insecticide DDT and benzene hexachloride? Why is their use banned in India and other countries?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

How will you obtain monobromobenzene from aniline?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

How can you obtain iodoethane from ethanol when no other iodine-containing reagent except NaI is available in the laboratory?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Match the compounds given in Column I with the effects given in Column II.

  Column I Column II
(i) Chloramphenicol (a) Malaria
(ii) Thyroxine (b) Anaesthetic
(iii) Chloroquine (c) Typhoid fever
(iv) Chloroform (d) Goiter
    (e) Blood substituent
[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Assertion: It is difficult to replace chlorine by –OH in chlorobenzene in comparison to that in chloroethane.

Reason: Chlorine-carbon \[\ce{(C - Cl)}\] bond in chlorobenzene has a partial double bond character due to resonance.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Some halogen containing compounds are useful in daily life. Some compounds of this class are responsible for exposure of flora and fauna to more and more of UV light which causes destruction to a great extent. Name the class of these halocompounds. In your opinion, what should be done to minimise harmful effects of these compounds.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

The reagent which does not react with both, acetone and benzaldehyde.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Which is the most suitable reagent for the following conversion?

\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Through which of the following reactions number of carbon atoms can be increased in the chain?

(i) Grignard reaction

(ii) Cannizaro’s reaction

(iii) Aldol condensation

(iv) HVZ reaction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Match the reactions given in Column I with the suitable reagents given in Column II.

Column I
(Reactions)
Column II
(Reagents)
(i) Benzophenone Diphenylmethane (a) \[\ce{LiAlH4}\]
(ii) Benzaldehyde 1-Phenylethanol (b) \[\ce{DIBAL-H}\]
(iii) Cyclohexanone Cyclohexanol (c) \[\ce{Zn(Hg)/Conc. HCl}\]
(iv) Phenyl benzoate Benzaldehyde (d) \[\ce{CH3MgBr}\]
[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.

Reason: Both, aldehydes and ketones contain a carbonyl group.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Arenium ion involved in the bromination of aniline is:

(i)

(ii)

(iii)

(iv)

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Why is benzene diazonium chloride not stored and is used immediately after its preparation?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Why does acetylation of –NH2 group of aniline reduce its activating effect?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Predict the product of reaction of aniline with bromine in non-polar solvent such as \[\ce{CS2}\].

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Why is aniline soluble in aqueous HCl?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined
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