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Question
Write the order of thermal stability of the hydrides of Group 16 elements.
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Solution 1
The thermal stability of hydrides decreases on moving down the group. This is due to a decrease in the bond dissociation enthalpy (H−E) of hydrides on moving down the group.
Therefore,
Solution 2
The thermal stability of hydrides of group 16 elements decreases down the group. This is because down the group, size of the element (M) increases, M-H bond length increases and thus, stability of M-H bond decreases so that it can be broken down easily. Hence, we have order of thermal stability as H2O > H2S > H2Se > H2Te > H2PQ
RELATED QUESTIONS
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3 ionisation enthalpy
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Statement II: On the basis of molecular mass, H2O is expected to have a lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has a higher boiling point.
In the light of the above statements, choose the correct answer from the options given below:
