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प्रश्न
Write the order of thermal stability of the hydrides of Group 16 elements.
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उत्तर १
The thermal stability of hydrides decreases on moving down the group. This is due to a decrease in the bond dissociation enthalpy (H−E) of hydrides on moving down the group.
Therefore,
उत्तर २
The thermal stability of hydrides of group 16 elements decreases down the group. This is because down the group, size of the element (M) increases, M-H bond length increases and thus, stability of M-H bond decreases so that it can be broken down easily. Hence, we have order of thermal stability as H2O > H2S > H2Se > H2Te > H2PQ
संबंधित प्रश्न
Account for the following: Oxygen shows catenation behavior less than sulphur.
a. Explain the trends in the following properties with reference to group 16:
1 Atomic radii and ionic radii
2 Density
3 ionisation enthalpy
4 Electronegativity
b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)
Give reasons: SO2 is reducing while TeO2 is an oxidising agent.
Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.
Give reasons for the following : H2Te is the strongest reducing agent amongst all the hydrides of Group 16 elements.
Why is H2O a liquid and H2S a gas?
Which of the following does not react with oxygen directly?
Zn, Ti, Pt, Fe
Why does NH3 form hydrogen bond but PH3 does not?
Why are halogens strong oxidising agents?
Arrange the following in order of the property indicated set.
HF, HCl, HBr, HI - decreasing bond enthalpy.
The formation of \[\ce{O^+_2[PtF6]^-}\] is the basis for the formation of first xenon compound. This is because ____________.
Which of the following statement is incorrect?
Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): Electron gain enthalpy of oxygen is less than that of Flourine but greater than Nitrogen.
Reason (R): Ionisation enthalpies of the elements follow the order Nitrogen > Oxygen > Fluorine.
Select the most appropriate answer from the options given below:
Strong reducing behaviour of \[\ce{H3PO2}\] is due to ______.
The correct order of ΔiHs among the following elements is
These are physical properties of an elements.
- Sublimation enthalpy
- Ionisation enthalpy
- Hydration enthalpy
- Electron gain enthalpy
The total number of above properties that affect the reduction potential is ______. (Integer answer)
______ is a gaseous element of group 16.
